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Equilivalent amounts of H(2) and I(2) ar...

Equilivalent amounts of `H_(2)` and `I_(2)` are heated in a closed vessel till equilibrium is obtained. If `80%` of the hydrogen is converted to `HI`, the `K_(c)` at this temperature is

A

64

B

16

C

0.25

D

14

Text Solution

Verified by Experts

The correct Answer is:
A

`{:(,H_(2),+,I_(2),hArr,2HI),("Initial",a" mol",,a " mol",,),("At eqm.",a-0.8a=2a,,0-0.8=0.2a,,2xx0.8a=1.6a),("Molar conc.",(0.2a)/(V),,(0.2a)/(V),,(1.6a)/(V)):}`
`K_(c)=([HI]^(2))/([H_(2)][I_(2)])=((1.6a//V)^(2))/((0.2a//V)(0.20//V))`
`=((16)^(2))/((0.2)^(2))=(2.56)/(0.04)=64`
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