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A compound can be divided into two equal...

A compound can be divided into two equal halves & contains even 'n' asymmetric carbon atoms. The number of optical isomer is –

A

`2^(n)`

B

`2^(n-1)`

C

`2^((n//2-1))`

D

`2^(n-1) + 2^((n//2-1))`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of determining the number of optical isomers for a compound with an even number of asymmetric (chiral) carbon atoms that can be divided into two equal halves, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Number of Chiral Carbons (n)**: - The problem states that the compound contains an even number of asymmetric carbon atoms. Let's denote this number as \( n \). 2. **Determine the Type of Compound**: - Since the compound can be divided into two equal halves, it indicates that it has a plane of symmetry. This means that the compound has meso forms. 3. **Use the Formula for Optical Isomers**: - For compounds with chiral centers that can be divided into two equal halves (and have an even number of chiral centers), the formula to calculate the number of optical isomers is: \[ \text{Number of Optical Isomers} = 2^{n-1} \] - Here, \( n \) is the number of chiral carbon atoms. 4. **Calculate the Number of Optical Isomers**: - Since \( n \) is even, we can substitute \( n \) into the formula. For example, if \( n = 2 \), the number of optical isomers would be: \[ 2^{2-1} = 2^1 = 2 \] - If \( n = 4 \), the number of optical isomers would be: \[ 2^{4-1} = 2^3 = 8 \] - This pattern continues for any even \( n \). 5. **Conclusion**: - Thus, the number of optical isomers for a compound with an even number of asymmetric carbon atoms that can be divided into two equal halves is given by \( 2^{n-1} \). ### Final Answer: The number of optical isomers is \( 2^{n-1} \).
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  2. Which of the following compounds may not exist as enantiomers?

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  3. Meso form of tartaric acid is –

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  4. How many asymmetric carbon atoms are present in - (i) 1,2-dimethyl c...

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  5. The number of geometrical isomers of CH(3)CH=CH-CH=CH-CH=CHCl is -

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  6. The number of optically active isomer possible for CH(3)-underset(OH)u...

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  7. A compound can be divided into two equal halves & contains even 'n' as...

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  8. Number of optically active isomers of tartaric acid is – underset(C...

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  9. Isomers which can be interconverted through rotation around a single b...

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  10. CH(3)-CH(2)-CH(2)-CH(3). There is free rotation about (C(2)ul(sigma)C(...

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  11. The total number of conformations of ethane is:

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  12. The eclipsed and staggered conformation of ethane is due to -

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  13. What are the type of isomers in following pairs-

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  14. At room temperature the eclipsed and the staggered forms of ethane can...

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  15. The phenomenon involving the migration of a proton to give two structu...

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  16. Which of the following compounds can exhibit tautomerism

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  17. Tautomerism is exhibited by -

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  18. Ethyl acetoacetate shows -

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  19. Which of the following does not show tautomerism ?

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  20. Which of the following shows tautomerism ?

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