Home
Class 12
CHEMISTRY
Write cell reaction of the following cel...

Write cell reaction of the following cells :
`Pt,H_2|H^+(aq)||Cd^(2+)(aq)|Cd`

Text Solution

AI Generated Solution

The correct Answer is:
To write the cell reaction for the given electrochemical cell represented as `Pt, H2 | H+(aq) || Cd^(2+)(aq) | Cd`, we can break it down into two half-reactions: oxidation and reduction. ### Step-by-Step Solution: 1. **Identify the Anode and Cathode:** - In this cell representation, the anode is on the left side (where oxidation occurs) and the cathode is on the right side (where reduction occurs). - Anode: Platinum electrode with H2 gas. - Cathode: Cadmium electrode with Cd²⁺ ions in solution. 2. **Write the Oxidation Half-Reaction (Anode):** - At the anode, hydrogen gas (H2) is oxidized to hydrogen ions (H⁺). - The oxidation reaction can be written as: \[ \text{H}_2(g) \rightarrow 2\text{H}^+(aq) + 2e^- \] - Here, 2 electrons are released during the oxidation of H2. 3. **Write the Reduction Half-Reaction (Cathode):** - At the cathode, cadmium ions (Cd²⁺) are reduced to solid cadmium (Cd). - The reduction reaction can be written as: \[ \text{Cd}^{2+}(aq) + 2e^- \rightarrow \text{Cd}(s) \] - Here, 2 electrons are consumed during the reduction of Cd²⁺. 4. **Combine the Half-Reactions:** - Now, we can combine the oxidation and reduction half-reactions to write the overall cell reaction. - The electrons cancel out, leading to the overall reaction: \[ \text{H}_2(g) + \text{Cd}^{2+}(aq) \rightarrow 2\text{H}^+(aq) + \text{Cd}(s) \] ### Final Cell Reaction: \[ \text{H}_2(g) + \text{Cd}^{2+}(aq) \rightarrow 2\text{H}^+(aq) + \text{Cd}(s) \]
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    MOTION|Exercise EXERCISE-4,I|30 Videos
  • ELECTROCHEMISTRY

    MOTION|Exercise EXERCISE-4,II|44 Videos
  • ELECTROCHEMISTRY

    MOTION|Exercise EXERCISE -2 (LEVEL-2)|26 Videos
  • D-BLOCK ELEMENTS

    MOTION|Exercise Exercise IV Level-II|9 Videos
  • GASEOUS STATE

    MOTION|Exercise EXERCISE-4( LEVEL-II)|19 Videos

Similar Questions

Explore conceptually related problems

Write cell reaction of the following cells : Pt,Cl_2|Cl^-(aq)||Ag^(+)aq_|Ag

Write cell reaction of the following cells: (a). Pt|Fe^(2+),Fe^(3+)||MnO_(4)^(-),Mn^(2+),H^(+)|Pt (b). Pt,Cl_(2)|Cl^(-)(aq)||Ag^(+)(aq)|Ag

Write the cell reactions for the following cells : (a) Fe|Fe^(2+)||H_(2)SO_(4)|H_(2)(Pt) (b) (Pt)H_(2)|HCl||Cl_(2)(Pt)

Write cell representation for following cells Cd^(2+)(aq)+Zn(s)toZn^(2+)(aq)+Cd(s)

Write Nernst equation for the following cell reaction : Zn(s) | Zn^(2+)(aq)|| Cu^(2+)(aq) | Cu(s)

Write the cell reaction for the following cell representation Zn//Zn_((aq))^(+2)////Ag_((aq))^(+)//Ag_((s))

Make complete cell diagrams of the following cell reactions (a). Cd^(2)(aq)+Zn(s)toZn^(2+)(aq)+Cd(s) (b). 2Ag^(+)(aq)+H_(2)(g)to2H^(+)(aq)+2Ag(s) (c). Hg_(2)Cl_(2)(s)+Cu(s)toCu^(2+)(aq)+2Cl^(-)(aq)+2Hg(l) (d). Cu_(2)O_(7)^(2-)(aq)+14H^(+)(aq)+6Fe^(2+)(aq)to6Fe^(3+)(aq)+2Cr^(3+)(aq)+7H_(2)O(l)

MOTION-ELECTROCHEMISTRY-EXERCISE-3
  1. Write cell reaction of the following cells: (a). Pt|Fe^(2+),Fe^(3+)|...

    Text Solution

    |

  2. Write cell reaction of the following cells : Pt,Cl2|Cl^-(aq)||Ag^(+)...

    Text Solution

    |

  3. Write cell reaction of the following cells : Pt,H2|H^+(aq)||Cd^(2+)(...

    Text Solution

    |

  4. Write cell representation for following cells Cd^(2+)(aq)+Zn(s)toZn^...

    Text Solution

    |

  5. Write cell representation for following cells 2Ag^+(aq)+H2(g)to 2H^+...

    Text Solution

    |

  6. Write cell representation for following cells Cr2O2^(2-)(a)+14H^+(aq...

    Text Solution

    |

  7. For the reaction : 2Ce^(4+)+Co rarr 2Ce^(3+)+Co^(2+), E(cell)^(@) = 1....

    Text Solution

    |

  8. Determine the standard reduction potential for the half reaction : C...

    Text Solution

    |

  9. Is 1.0 M H^+ solution under H2SO4 at 1.0 atm capable of oxidising silv...

    Text Solution

    |

  10. If for the half reactions Cu^(2+)+e^- to Cu^+" "E^0=0.15V ...

    Text Solution

    |

  11. If E(Fe^(2+)|Fe)^0=-0.44V,E((Fe^3+)||Fe^(2+))^0=0.77. Calculate E(Fe^(...

    Text Solution

    |

  12. Calculate the EMF of a Daniel cell when the concentartion of ZnSO(4) a...

    Text Solution

    |

  13. For the cell reaction, Mg|Mg^(2+) (aq.)||Ag^(+) (aq.)|Ag calculate...

    Text Solution

    |

  14. The EMF of the cell M|M^(n+)(0.2M)||H^(+)(1M)|H(2)(g)(1atm), Pt at 25^...

    Text Solution

    |

  15. Equinormal solutions of two weak acids HA(pK(a)=3) and HB(pK(a)=5) are...

    Text Solution

    |

  16. Calculate E^0 and E for the cell Sn||Sn^(@+)(1M)||Pb^(2+)(10^(-3)M)|Pb...

    Text Solution

    |

  17. At what concentration of Cu^(2+) in a solution of CuSO4 will be electr...

    Text Solution

    |

  18. A zinc electrode is placed in 0.1M solution of ZnSO(4) at 25^(@)C. Ass...

    Text Solution

    |

  19. Calcualte the EMF of the following cell Zn|Zn^(2+)(0.01M)||Zn^(2+)(0...

    Text Solution

    |

  20. Calcualte the EMF of the cellj Zn-Hg(c1M)|Zn^(2+)(aq)|Hg-Zn(c2M) a...

    Text Solution

    |