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10 gm of oxygen at a pressure 3 xx 10^5 ...

10 gm of oxygen at a pressure `3 xx 10^5 N//m^2` and temperature `10^@C` is heated at constant pressure and after heating it occupies a volume of 10 litres. (a) Find the amount of heat received by the gas and (b) the energy of thermal motion of gas molecules before heating.

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To solve the problem step by step, let's break it down into two parts as per the question. ### Part (a): Find the amount of heat received by the gas. 1. **Identify the given data:** - Mass of oxygen, \( m = 10 \, \text{g} = 0.01 \, \text{kg} \) - Pressure, \( P = 3 \times 10^5 \, \text{N/m}^2 \) - Initial temperature, \( T_1 = 10^\circ C = 283 \, \text{K} \) (Convert to Kelvin by adding 273) - Final volume, \( V = 10 \, \text{liters} = 0.01 \, \text{m}^3 \) 2. **Calculate the number of moles of oxygen:** - Molar mass of oxygen, \( M = 32 \, \text{g/mol} \) - Number of moles, \( N = \frac{m}{M} = \frac{10 \, \text{g}}{32 \, \text{g/mol}} = 0.3125 \, \text{mol} \) 3. **Use the ideal gas law to find the final temperature:** - The ideal gas equation is \( PV = nRT \) - Rearranging gives \( T_2 = \frac{PV}{nR} \) - Using \( R = 8.314 \, \text{J/(mol K)} \): \[ T_2 = \frac{(3 \times 10^5 \, \text{N/m}^2)(0.01 \, \text{m}^3)}{0.3125 \, \text{mol} \times 8.314 \, \text{J/(mol K)}} \] - Calculate \( T_2 \): \[ T_2 = \frac{3000}{2.604375} \approx 115.1 \, \text{K} \approx 585.65 \, \text{K} \] 4. **Calculate the change in temperature:** \[ \Delta T = T_2 - T_1 = 585.65 \, \text{K} - 283 \, \text{K} = 302.65 \, \text{K} \] 5. **Calculate the heat received by the gas at constant pressure:** - For an ideal gas, the heat absorbed at constant pressure is given by: \[ Q = N C_P \Delta T \] - Where \( C_P = \frac{7}{2} R \): \[ C_P = \frac{7}{2} \times 8.314 \approx 29.19 \, \text{J/(mol K)} \] - Now substituting the values: \[ Q = 0.3125 \, \text{mol} \times 29.19 \, \text{J/(mol K)} \times 302.65 \, \text{K} \] - Calculate \( Q \): \[ Q \approx 0.3125 \times 29.19 \times 302.65 \approx 54.2 \, \text{J} \] ### Part (b): Find the energy of thermal motion of gas molecules before heating. 1. **Calculate the internal energy before heating:** - The internal energy \( U \) of an ideal gas is given by: \[ U = N C_V T \] - Where \( C_V = \frac{5}{2} R \): \[ C_V = \frac{5}{2} \times 8.314 \approx 20.79 \, \text{J/(mol K)} \] - Now substituting the values: \[ U = 0.3125 \, \text{mol} \times 20.79 \, \text{J/(mol K)} \times 283 \, \text{K} \] - Calculate \( U \): \[ U \approx 0.3125 \times 20.79 \times 283 \approx 38.7 \, \text{J} \] ### Final Answers: (a) The amount of heat received by the gas is approximately **54.2 J**. (b) The energy of thermal motion of gas molecules before heating is approximately **38.7 J**.
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