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A gram mole of a gas at 27^@C expands is...

A gram mole of a gas at `27^@C` expands isothermally until its volume is doubled. Calculate the amount of work done. `(R=8 J mol^(-1) K^(-1))`

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To solve the problem of calculating the work done when a gram mole of gas expands isothermally until its volume is doubled, we can follow these steps: ### Step-by-Step Solution: 1. **Convert Temperature to Kelvin**: The given temperature is \(27^\circ C\). To convert this to Kelvin, we use the formula: \[ T(K) = T(°C) + 273 \] \[ T = 27 + 273 = 300 \, K \] 2. **Identify Given Values**: - Number of moles, \(n = 1 \, \text{mol}\) - Gas constant, \(R = 8 \, \text{J mol}^{-1} \text{K}^{-1}\) - Initial volume \(V_1\) and final volume \(V_2\) where \(V_2 = 2V_1\). 3. **Use the Work Done Formula for Isothermal Expansion**: The work done \(W\) during an isothermal expansion can be calculated using the formula: \[ W = nRT \ln\left(\frac{V_2}{V_1}\right) \] Since \(V_2 = 2V_1\), we have: \[ \frac{V_2}{V_1} = 2 \] 4. **Substitute the Values into the Formula**: Now we can substitute the known values into the work done formula: \[ W = 1 \, \text{mol} \times 8 \, \text{J mol}^{-1} \text{K}^{-1} \times 300 \, K \times \ln(2) \] 5. **Calculate \(\ln(2)\)**: The natural logarithm of 2 is approximately: \[ \ln(2) \approx 0.6932 \] 6. **Calculate the Work Done**: Now substituting \(\ln(2)\) into the equation: \[ W = 1 \times 8 \times 300 \times 0.6932 \] \[ W = 2400 \times 0.6932 \approx 1663.68 \, J \] 7. **Final Result**: The work done during the isothermal expansion is: \[ W \approx 1.66 \times 10^3 \, J \] ### Final Answer: The amount of work done is approximately \(1.66 \times 10^3 \, J\).
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PHYSICS GALAXY - ASHISH ARORA-THERMODYNAMICS LAWS & SPECIFIC HEATS OF GASES -Unsolved Numerical Problems
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