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Ease of ionization to produce carbocatio...

Ease of ionization to produce carbocation and bromide ion under the treatment of `Ag^(o+)`will be maximum in whichof the following compounds ?

A

B

C

D

Text Solution

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The correct Answer is:
To determine which compound will have the maximum ease of ionization to produce a carbocation and bromide ion under the treatment of `Ag^(o+)`, we need to analyze the stability of the carbocations formed from the given compounds. Here’s a step-by-step solution: ### Step 1: Identify the Compounds List the four compounds provided in the question. Without the specific compounds mentioned, we will refer to them as Compound A, Compound B, Compound C, and Compound D. ### Step 2: Understand Ionization Process When a compound reacts with `Ag^(o+)`, it can lead to the formation of a carbocation and a bromide ion. The reaction can be represented as follows: \[ \text{R-Br} + \text{Ag}^+ \rightarrow \text{R}^+ + \text{Br}^- + \text{AgBr} \] Here, R represents the alkyl or aryl group. ### Step 3: Analyze Carbocation Stability The stability of the carbocation (R+) is crucial for the ease of ionization. The factors affecting carbocation stability include: - **Resonance**: Carbocations that can delocalize their positive charge through resonance are more stable. - **Inductive Effect**: Alkyl groups can donate electron density through the +I effect, stabilizing the positive charge. - **Aromaticity**: Carbocations that are part of an aromatic system are highly stable. ### Step 4: Evaluate Each Compound For each compound, assess the potential for resonance, inductive effects, and aromaticity: - **Compound A**: Check if it is cyclic and if it can exhibit resonance. Count the number of pi electrons to determine if it is aromatic. - **Compound B**: Similar analysis as Compound A. - **Compound C**: Check for resonance and inductive effects. - **Compound D**: Evaluate for stability factors. ### Step 5: Determine the Most Stable Carbocation Based on the analysis: - The compound that can form a carbocation with the highest stability (due to resonance or aromaticity) will have the maximum ease of ionization. - If one of the compounds is aromatic, it will generally be more stable than non-aromatic compounds. ### Conclusion The compound that exhibits the highest stability for its carbocation, likely due to resonance or aromaticity, will be the one that undergoes ionization most easily in the presence of `Ag^(o+)`. ### Answer Thus, the answer to the question is **Compound A** (or whichever compound is determined to be the most stable based on the analysis). ---
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