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Aromatic compounds are:...

Aromatic compounds are:

A

B

C

D

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To determine which compounds are aromatic, we need to follow certain criteria. Let's break down the steps to analyze the given compounds based on the criteria for aromaticity. ### Step-by-Step Solution: 1. **Understand the Criteria for Aromaticity**: - The compound must follow Hückel's rule, which states that it should have \(4n + 2\) π electrons, where n is a non-negative integer (0, 1, 2, ...). - The compound must be cyclic (form a ring). - The compound must be planar (all atoms in the same plane). - The compound must have complete conjugation (p-orbitals must overlap). 2. **Analyze Each Compound**: - **Compound A**: - It has 6 π electrons (which fits \(n=1\) in \(4n + 2\)). - It is cyclic and planar. - It has complete conjugation. - **Conclusion**: Compound A is aromatic. - **Compound B**: - It has 6 π electrons (again fits \(n=1\)). - It is cyclic and planar. - The lone pair can participate in resonance, contributing to the π system. - **Conclusion**: Compound B is aromatic. - **Compound C**: - It has 4 π electrons (which fits \(n=0\) in \(4n\)). - It is cyclic but does not have complete conjugation. - **Conclusion**: Compound C is anti-aromatic (not aromatic). - **Compound D**: - It has 6 π electrons (fits \(n=1\)). - It is cyclic and planar. - The negative charge does not participate in delocalization but does not affect the aromaticity as long as there are 6 π electrons and complete conjugation. - **Conclusion**: Compound D is aromatic. 3. **Final Summary**: - The aromatic compounds from the options are A, B, and D. - Compound C is anti-aromatic. ### Final Answer: The aromatic compounds are A, B, and D. ---
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