Home
Class 12
CHEMISTRY
NO(2) readily dimenise, whereas ClO(2) d...

`NO_(2)` readily dimenise, whereas `ClO_(2)` does not. Why ?

Text Solution

AI Generated Solution

To understand why \( NO_2 \) readily dimerizes while \( ClO_2 \) does not, we can break down the explanation into several steps: ### Step 1: Identify the Central Atoms - The central atom in \( NO_2 \) is nitrogen (N), and in \( ClO_2 \) it is chlorine (Cl). ### Step 2: Compare the Sizes of the Central Atoms - Nitrogen is smaller in size compared to chlorine. This is due to the position of these elements in the periodic table. As we move down a group in the periodic table, the atomic size increases because additional electron shells are added. ...
Promotional Banner

Topper's Solved these Questions

  • P-BLOCK ELEMENTS

    CBSE COMPLEMENTARY MATERIAL|Exercise SHORT ANSWER-II TYPE QUESTIONS|34 Videos
  • P-BLOCK ELEMENTS

    CBSE COMPLEMENTARY MATERIAL|Exercise VERY SHORT ANSWER TYPE QUESTIONS|42 Videos
  • P-BLOCK ELEMENTS

    CBSE COMPLEMENTARY MATERIAL|Exercise LONG ANSWER TYPE QUESTIONS|15 Videos
  • HALOALKANES AND HALOARENES

    CBSE COMPLEMENTARY MATERIAL|Exercise CONCEPTUAL QUESTIONS|10 Videos
  • POLYMERS

    CBSE COMPLEMENTARY MATERIAL|Exercise LONG ANSWER TYPE QUESTIONS|5 Videos

Similar Questions

Explore conceptually related problems

Why does He_2^+ exist whereas He_2 does not ?

KHF_(2) is a well known compound whereas KHCl_(2) does not exist. Why ?

Fluorine does not form oxyacid, but other halogens do. Why? (b) Both NO and ClO_(2) are odd electron species. NO dimeries but ClO_(2) does not . Why?

NO_2 forms dimer but ClO_2 does not why?

Assertion : NO_(2) is readily dimerised to N_(2)O_(4) Reason : NO_(2) has one unpaired electron and two such electron with opposite spin in two NO_(2) molecules form bond between two N-atoms readily.

The molecule of CO_(2) is linear whereas that of SnCl_(2) is angular why?

Na_(2)CO_(3) does not decompose on heating whereas CaCO_(3) decomposes . Why ?

Why does NO_(2) dimerise ?

CBSE COMPLEMENTARY MATERIAL-P-BLOCK ELEMENTS-SHORT ANSWER-I TYPE QUESTIONS
  1. What happens when NaCl is heated with conc. H(2)SO(4) in the presence ...

    Text Solution

    |

  2. A colourless pungent smelling gas, which easily liquefies to a colourl...

    Text Solution

    |

  3. NO(2) readily dimenise, whereas ClO(2) does not. Why ?

    Text Solution

    |

  4. Compare the oxidizing powers of F(2) and Cl(2) on the basis of bond di...

    Text Solution

    |

  5. Which fluorinating agent are oftenly used instead of F(2) ? Write chem...

    Text Solution

    |

  6. Draw the structure of BrF(3).

    Text Solution

    |

  7. Complete the following reactions : Al(2)O(3)(s)+NaOH(aq)+H(2)O(l)rar...

    Text Solution

    |

  8. Complete the following reactions : HCl+O(2)rarr

    Text Solution

    |

  9. Complete the following reactions : Ca(OH)(2)+Cl(2)rarr

    Text Solution

    |

  10. Complete the following reactions : N(2)("excess")+Cl(2)rarr

    Text Solution

    |

  11. Complete the following reactions : Na(2)SO(3)+Cl(2)+H(2)Orarr

    Text Solution

    |

  12. Complete the following reactions : NH(3)+Cl(2)("excess")rarr

    Text Solution

    |

  13. Complete the following reactions : Cl(2) + NaOH ("cold & dil.") →

    Text Solution

    |

  14. Complete the following equations : (i) underset(("hot and conc."))(N...

    Text Solution

    |

  15. Complete the following reactions : Fe+HClrarr

    Text Solution

    |

  16. Cl(2)+F(2) ("excess") to

    Text Solution

    |

  17. Complete the following reactions : U + ClF(3) →

    Text Solution

    |

  18. Complete the following reactions : FeSO(4) + H(2)SO(4) + Cl(2) →

    Text Solution

    |

  19. Draw the structure of : I(3)^(−)

    Text Solution

    |

  20. Draw the structure of : ICl(2)^(−).

    Text Solution

    |