Home
Class 11
CHEMISTRY
To a solution of excess of KI in dilute ...

To a solution of excess of KI in dilute `H_(2)SO_(4)`. 25 mL of an unknown solution of `KMnO_(4)` were added. The liberated iodine was exactly reduced by 42.5 mL of `N//10 Na_(2)S_(2)O_(3)` solution. Calculate the concentration of `KMnO_(4)` solution.

Text Solution

Verified by Experts

The correct Answer is:
`5.372 g//L`
Promotional Banner

Topper's Solved these Questions

  • VOLUMETRIC ANALYSIS

    OP TANDON|Exercise Objective Question (Level-A)|99 Videos
  • VOLUMETRIC ANALYSIS

    OP TANDON|Exercise Objective Question (Level-B)|38 Videos
  • VOLUMETRIC ANALYSIS

    OP TANDON|Exercise Illustrations|20 Videos
  • THE COLLOIDAL STATE

    OP TANDON|Exercise Self Assessment|21 Videos

Similar Questions

Explore conceptually related problems

To a 25 mL H_2 O_2 solution, excess of acidified solution of KI was added. The iodine liberated required 20.0 mL of 0.3 N Na_2 S_2 O_3 solution. Calculate the volume strength of H_2 O_2 solution.

50 mL of an aqueous solution of H_(2)O_(2) was treated with an excess of KI solution and dilute H_(2)SO_(4) . The liberated iodine required 20 mL 0.1 N Na_(2)S_(2)O_(3) solution for complete interaction. Calculate the concentration of H_(2)O_(2) in g//L .

To a 25 mL of H_(2)O_(2) solution, excess of acidified solution of KI was added. The iodine liberated required 20 mL of 0.3 N Na_(2)S_(2)O_(3) solution. Calculate the volume strength of H_(2)O_2 solution. Strategy : Volume strength of H_(2)O_(2) solution is related to its normality by the following relation Volume strength (V)=5.6xx"Normality" (N) where, Normality =((meq)H_(2)O_(2))/V_(mL) According to the law of equivalence (meq)_(Na_(2)S_(2)O_(3))=(meq)_(I_(2))=(meq)_(H_(2)O_(2))

A sample of MnSO_(4). 4H_(2)O is strongly heated in air. The residue ( Mn_(3)O_(4)) left was dissolved in 100 mL of 0.1NFeSO_94) containing dil. H_(2)SO_(4) . This solution was completely reacted with 50 mL of KMnO_(4) solution. 25 mL of this KMnO_(4) solution was completely reduced by 30 mL of 0.1N FeSO_(4) solution. Calculate the amount of MnSO_(4).4H_(2)O in sample.

OP TANDON-VOLUMETRIC ANALYSIS-Practice Problems
  1. 1 g of the complex [Cr(H(2)O)(5)Cl]Cl(2). H(2)O was passed through a c...

    Text Solution

    |

  2. 5.0 g of bleaching powder was suspended in water and volume made up to...

    Text Solution

    |

  3. To a solution of excess of KI in dilute H(2)SO(4). 25 mL of an unknown...

    Text Solution

    |

  4. In 20 mL of a solution of HCl, 3 g of CaCO(3) were dissolved, 0.5 g of...

    Text Solution

    |

  5. 1.0 litre of a solution contains 5.3 g of Na(2)CO(3) and 8 g of NaOH. ...

    Text Solution

    |

  6. To 20 mL of a copper solution after necessary treatment were added exc...

    Text Solution

    |

  7. 0.28 g of a commercial sample of K(2)Cr(2)O(7) was dissolved in water....

    Text Solution

    |

  8. A mixture containing KCl and NaCl was dissolved and total halide was d...

    Text Solution

    |

  9. 1.355 g of pyrolusite sample are added to 50 mL of 1 N oxalic acid sol...

    Text Solution

    |

  10. 0.5 g of bleaching powder was suspended in water an excess of KI added...

    Text Solution

    |

  11. Calculate the number of oxalic acid molecules in 100 mL of 0.02 N oxal...

    Text Solution

    |

  12. 1.26 g of a dibasic acid were dissovled in water and made up to 200 mL...

    Text Solution

    |

  13. 3.0 g of a sample of impure ammonium chloride were boiled with excess ...

    Text Solution

    |

  14. 2.20 g of an ammonium salt were boiled with 75 mL of NaOH till the emi...

    Text Solution

    |

  15. 3.45 g of a metallic carbonate were mixed with 240 mL of N//4 HCl. The...

    Text Solution

    |

  16. (a) 2 g of metal carbonate were dissolved in 50 mL of N HCl. 100 mL of...

    Text Solution

    |

  17. Upon mixing 45.0 mL of 0.25 M lead nitrate solution with 25 mL of 0.1 ...

    Text Solution

    |

  18. In an ore the only oxidisable material is Sn^(2+). This ore is titrate...

    Text Solution

    |

  19. 2.26 g of impure ammonium chloride were boiled with 100 mL of NaOH sol...

    Text Solution

    |

  20. Metallic tin in the presence of HCl is oxidised by K(2)Cr(2)O(7) solut...

    Text Solution

    |