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A solution containing 10 g per dm^(3) of...

A solution containing `10 g per dm^(3)` of urea (mol.wt. `= 60 g mol^(-1)`) is isotonic with a `5%` ( mass//vol.) of a non-volatile solute. The molecular mass of non-volatile solute is:

A

`"250 g mol"^(-1)`

B

`"300 g mol"^(-1)`

C

`"350 g mol"^(-1)`

D

`"200 g mol"^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
B

`pi_(1)` (urea) = `pi_(2)` (unknown solute)
`C_(1)` (urea) = `C_(2)` (unknown solute)
`[(w_(B)xx1000)/(m_(B)xxV)]_("urea")=[(w_(B)xx1000)/(m_(B)xxV)]_("unknown solute")`
`(10xx1000)/(60xx1000)=(5xx1000)/(m_(B)xx100)`
`m_(B)=300 "g mol"^(-1)`]
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