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Which one of the following salts will ha...

Which one of the following salts will have the same value of van't hoff factor (i) as that of `K_(4)[Fe(CN)_(6)]`?

A

`AI_(2)(SO_(4))_(3)`

B

`NaCI`

C

`AI(NO_(3))_(3)`

D

`Na_(2)SO_(4)`

Text Solution

Verified by Experts

The correct Answer is:
A

`K_(4)[Fe(CN)_(6)]` dissociates as `4K^(+) +[Fe(CN)_(6)]^(4+)` Thus 1 molecule dissociates into five particles. In the similar way `AI_(2)(SO_(4))_(3)` also give five particles per molecule.
`AI_(2)(SO_(4))_(3) rarr 2AI^(3+) +3 SO_(4)^(2-)`
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