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The dissociation constant of monobasic a...

The dissociation constant of monobasic acids `A, B,C` and `D` are `6 xx 10^(-4),5xx10^(-5), 3.6 xx 10^(-6)`, and `7 xx 10^(-10)`, respectively. The `pH` values of their `0.1M` aqueous solutions are in the order.

A

`HX gt HX gt HY gt HD`

B

`HDgtHYgtHXgtHA`

C

All the solutions have same pH

D

`HXgtHDgtHYgtHA`.

Text Solution

Verified by Experts

The correct Answer is:
B

`[H^(+)]=sqrt(KxxC)`. Thus for same value of C, larger the value of K, greater is `[H^(+)]`, hence lower is the value of pH.
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