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The expected shape of Br3^- ion is...

The expected shape of `Br_3^-` ion is

A

linear

B

trigonal planar

C

pyramidal

D

angular

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The correct Answer is:
To determine the expected shape of the `Br_3^-` ion, we will follow these steps: ### Step 1: Determine the Valence Electrons Bromine (Br) is in group 17 of the periodic table and has 7 valence electrons. Since there are three bromine atoms in the ion, we will calculate the total valence electrons contributed by bromine. - Total valence electrons from 3 Br = 3 × 7 = 21 electrons ### Step 2: Account for the Charge The `Br_3^-` ion has a negative charge, which means we need to add one additional electron to the total count. - Total valence electrons = 21 + 1 = 22 electrons ### Step 3: Calculate the Steric Number The steric number can be calculated using the formula: \[ \text{Steric Number} = \text{(Valence Electrons of Central Atom)} + \text{(Monovalent Atoms Attached)} + \text{(Anionic Charge)} \] In this case: - Central atom: 1 Br (7 valence electrons) - Monovalent atoms attached: 2 Br - Anionic charge: +1 So, the steric number calculation would be: \[ \text{Steric Number} = 7 + 2 + 1 = 10 \] ### Step 4: Determine Hybridization The steric number of 5 indicates the hybridization of the central atom. For a steric number of 5, the hybridization is \( sp^3d \). ### Step 5: Identify Lone Pairs In the `Br_3^-` ion, the central bromine atom will have 3 bonding pairs (with the two other bromine atoms) and 2 lone pairs of electrons. ### Step 6: Determine the Molecular Geometry According to VSEPR theory, when there are 5 regions of electron density (3 bonding pairs and 2 lone pairs), the molecular shape is determined by the positions of the bonding pairs. The lone pairs will occupy equatorial positions to minimize repulsion, leading to a trigonal bipyramidal arrangement. However, since we are only considering the positions of the bonded atoms for the shape, the molecular shape will be linear. ### Conclusion The expected shape of the `Br_3^-` ion is **linear**.

To determine the expected shape of the `Br_3^-` ion, we will follow these steps: ### Step 1: Determine the Valence Electrons Bromine (Br) is in group 17 of the periodic table and has 7 valence electrons. Since there are three bromine atoms in the ion, we will calculate the total valence electrons contributed by bromine. - Total valence electrons from 3 Br = 3 × 7 = 21 electrons ### Step 2: Account for the Charge ...
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Knowledge Check

  • Shape of ClO_(3)^(-) ion is

    A
    Pyramidal
    B
    Tetrahedral
    C
    angular
    D
    linear
  • The shape of SO_4^(2-) ion is

    A
    square planar
    B
    square pyramid
    C
    tetrahedral
    D
    none of these
  • Shape of ClO_(2)^(-) ion is

    A
    Liner
    B
    angular
    C
    pyramid
    D
    None
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