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Acetone overset(NH(2)OH)rarr X overset(L...

Acetone `overset(NH_(2)OH)rarr X overset(LiAIH_(4))rarr Y`. In the above sequence Y is

A

tertiary amine

B

secondary amine

C

primary amine

D

2-amino propane.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will analyze the reactions involved in the sequence provided. ### Step 1: Identify the Reaction of Acetone with Hydroxylamine Acetone (C₃H₆O) reacts with hydroxylamine (NH₂OH) to form an oxime. The reaction can be represented as follows: 1. **Starting Material**: Acetone (C₃H₆O) 2. **Reagent**: Hydroxylamine (NH₂OH) 3. **Reaction**: The carbonyl group (C=O) of acetone reacts with hydroxylamine, leading to the formation of acetoxime (X) and the release of water (H₂O). The reaction can be summarized as: \[ \text{C}_3\text{H}_6\text{O} + \text{NH}_2\text{OH} \rightarrow \text{C}_3\text{H}_7\text{NO} + \text{H}_2\text{O} \] Where: - Acetoxime (X) is formed: \[ \text{CH}_3\text{C}(=N\text{OH})\text{CH}_3 \] ### Step 2: Identify the Reaction of Acetoxime with Lithium Aluminum Hydride Next, we need to reduce the acetoxime (X) formed in the previous step using lithium aluminum hydride (LiAlH₄): 1. **Starting Material**: Acetoxime (C₃H₇NO) 2. **Reagent**: Lithium Aluminum Hydride (LiAlH₄) 3. **Reaction**: Lithium aluminum hydride is a strong reducing agent that will convert the oxime into a primary amine. The reaction will replace the oxime group (N=OH) with an amine group (NH₂). The reaction can be summarized as: \[ \text{C}_3\text{H}_7\text{NO} + \text{LiAlH}_4 \rightarrow \text{C}_3\text{H}_9\text{N} + \text{H}_2\text{O} \] Where: - The product (Y) formed is 2-aminopropane: \[ \text{CH}_3\text{C}(NH_2)\text{CH}_3 \] ### Final Answer Thus, the compound Y formed after the sequence of reactions is **2-aminopropane**.

To solve the problem step by step, we will analyze the reactions involved in the sequence provided. ### Step 1: Identify the Reaction of Acetone with Hydroxylamine Acetone (C₃H₆O) reacts with hydroxylamine (NH₂OH) to form an oxime. The reaction can be represented as follows: 1. **Starting Material**: Acetone (C₃H₆O) 2. **Reagent**: Hydroxylamine (NH₂OH) 3. **Reaction**: The carbonyl group (C=O) of acetone reacts with hydroxylamine, leading to the formation of acetoxime (X) and the release of water (H₂O). ...
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Knowledge Check

  • Isopropylamine overset(KMnO_(4))rarr X overset(H_(3)^(+)O)rarr Y In the above sequence X and Y are

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  • HC -= N + HCl overset(AlCl_(3))rarr X underset(AlCl_(3))overset(C_(6)H_(6))rarr Y overset(H_(2)O)rarr Z In the above sequence X, Y, Z is

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