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Acetone overset(NH(2)OH)rarr X overset(L...

Acetone `overset(NH_(2)OH)rarr X overset(LiAIH_(4))rarr Y`. In the above sequence Y is

A

tertiary amine

B

secondary amine

C

primary amine

D

2-amino propane.

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The correct Answer is:
To solve the problem step by step, we will analyze the reactions involved in the sequence provided. ### Step 1: Identify the Reaction of Acetone with Hydroxylamine Acetone (C₃H₆O) reacts with hydroxylamine (NH₂OH) to form an oxime. The reaction can be represented as follows: 1. **Starting Material**: Acetone (C₃H₆O) 2. **Reagent**: Hydroxylamine (NH₂OH) 3. **Reaction**: The carbonyl group (C=O) of acetone reacts with hydroxylamine, leading to the formation of acetoxime (X) and the release of water (H₂O). The reaction can be summarized as: \[ \text{C}_3\text{H}_6\text{O} + \text{NH}_2\text{OH} \rightarrow \text{C}_3\text{H}_7\text{NO} + \text{H}_2\text{O} \] Where: - Acetoxime (X) is formed: \[ \text{CH}_3\text{C}(=N\text{OH})\text{CH}_3 \] ### Step 2: Identify the Reaction of Acetoxime with Lithium Aluminum Hydride Next, we need to reduce the acetoxime (X) formed in the previous step using lithium aluminum hydride (LiAlH₄): 1. **Starting Material**: Acetoxime (C₃H₇NO) 2. **Reagent**: Lithium Aluminum Hydride (LiAlH₄) 3. **Reaction**: Lithium aluminum hydride is a strong reducing agent that will convert the oxime into a primary amine. The reaction will replace the oxime group (N=OH) with an amine group (NH₂). The reaction can be summarized as: \[ \text{C}_3\text{H}_7\text{NO} + \text{LiAlH}_4 \rightarrow \text{C}_3\text{H}_9\text{N} + \text{H}_2\text{O} \] Where: - The product (Y) formed is 2-aminopropane: \[ \text{CH}_3\text{C}(NH_2)\text{CH}_3 \] ### Final Answer Thus, the compound Y formed after the sequence of reactions is **2-aminopropane**.

To solve the problem step by step, we will analyze the reactions involved in the sequence provided. ### Step 1: Identify the Reaction of Acetone with Hydroxylamine Acetone (C₃H₆O) reacts with hydroxylamine (NH₂OH) to form an oxime. The reaction can be represented as follows: 1. **Starting Material**: Acetone (C₃H₆O) 2. **Reagent**: Hydroxylamine (NH₂OH) 3. **Reaction**: The carbonyl group (C=O) of acetone reacts with hydroxylamine, leading to the formation of acetoxime (X) and the release of water (H₂O). ...
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DINESH PUBLICATION-CYANIDES, ISOCYANIDES, NITROCOMPOUNDS AND AMINES-Unit test - 8
  1. Acetone overset(NH(2)OH)rarr X overset(LiAIH(4))rarr Y. In the above s...

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  2. Select incorrect statement

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  3. H(2)O is reduce with Sn//HCl. Product formed

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  4. RNH(2) can be converted into R, NH and no other amine by

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  5. Which is general order of basicity for water and amines

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  6. Consider following hydrogen-bonded amines I and II Select the cor...

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  7. Which is the strongest conjugate acid ?

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  8. When (CH(3))(3)CNH(3)^(+)Cl^(-) is heated, product is

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  9. Select correct statement (s), about the following reaction [(CH(3))(3)...

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  10. Major alkene of the following reaction is {:(CH(3)-C CH(2)CH(3)),(" ...

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  11. Exhaustive methylation of CH(3)CH(2)NH(2) forms

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  12. Following 2^(@) amine has chiral carbon as indicated H-underset(CH(3))...

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  13. Major product of the following reaction is {:(" "NH(...

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  14. Consider the following reaction underset((A))(CH(3)CONH(2)) overset(...

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  15. Which is soluble in NONO(2) and dil HCl mixture forming salt ?

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  16. Tertiary amine is oxidized to oxide by

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  17. Cope elimination is an intramolecular, E(2) reaction because

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  18. Cope elimination

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  19. In gas phase, the basicities of amines increase in the order NH(3) lt ...

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  20. In aqueous phase basicity of amines is in order NH(3) lt (CH(3))(3)N...

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  21. Which of the following chemicals are used to manufacture methyl isocya...

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