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In gaseous phase the decreasing order of...

In gaseous phase the decreasing order of basic nature of the three methyl amines is in the order

A

`3^(@) gt 2^(@) gt 1^(@)`

B

`1^(@) gt 2^(@) gt 3^(@)`

C

`2^(@) gt 1^(@) gt 3^(@)`

D

`2^(@) gt 3^(@) gt 1^(@)`

Text Solution

Verified by Experts

The correct Answer is:
A
In gaseous phase, there is no solvent effect. As such only the `+I` effect of the methyl group makes `3^(@)` amine most basic followed by `2^(@)` and `1^(@)`
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DINESH PUBLICATION-CYANIDES, ISOCYANIDES, NITROCOMPOUNDS AND AMINES-Brain Teasers -13
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