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[X]+H(2)SO(4) rarr [Y] a colourless gas ...

`[X]+H_(2)SO_(4) rarr [Y]` a colourless gas with irritating smell `[Y] + K_(2)Cr_(2)O_(7) + H_(2)SO_(4) rarr` green solution `[X]` and `[Y]` are

A

`SO_3^(2-), SO_2`

B

`Cl^(-) , HCl`

C

`S^(2-) , H_2S`

D

`CO_3^2, CO_2`

Text Solution

Verified by Experts

The correct Answer is:
A

`SO_3^(2)+underset(("from" H_2SO_4))(2H^(+))toSO_2+H_2O`
`3SO_2+Cr_2O_7^(2)+2H^(+)to3SO_4^(2)+underset(("green"))(2Cr^(3+))+H_2O`
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[X]+H_(2)SO_(4) to [Y] a colourless gas with irritating smell, [Y]+K_(2)Cr_(2)O_(7)+H_(2)SO_(4) to green solution. [X] and [Y] are respectively :

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DINESH PUBLICATION-THE OXYGEN FAMILY-Selected Straight objective
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