Home
Class 12
CHEMISTRY
Given that, Co^(3+) +e^(-)rarr Co^(2+) E...

Given that, `Co^(3+) +e^(-)rarr Co^(2+) E^(@) = +1.82 V`
`2H_(2)O rarr O_(2) +4H^(+) +4e^(-), E^(@) =- 1.23 V`.
Explain why `Co^(3+)` is not stable in aqueous solutions.

Text Solution

Verified by Experts

The `E_(cell)^(@)` can be calculated as follows :
Since `E_(cell)^(@)` is positive, the cell reaction is spontaneous. This means that `Co^(3+)` ion will take part in the reaction. Therefore, `Co^(3+)` is not stable in aqueous solution.
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    DINESH PUBLICATION|Exercise QUESTIONS FROM BOARD EXAMINATIONS|81 Videos
  • ELECTROCHEMISTRY

    DINESH PUBLICATION|Exercise HOTS|17 Videos
  • ELECTROCHEMISTRY

    DINESH PUBLICATION|Exercise LONG ANSWER TYPE QUESTIONS|3 Videos
  • D-AND -F BLOCK ELEMENTS

    DINESH PUBLICATION|Exercise BRAIN STORMING MULTIPLE CHOICE QUESTIONS (MCQS)|13 Videos
  • ETHERS

    DINESH PUBLICATION|Exercise (MCQs)|8 Videos

Similar Questions

Explore conceptually related problems

Given 2H_(2)O rarr O_2 + 4H^+ + 4e^- , E_0 = -1.23 V . Calculate electrode potential at pH = 5.

Redox reactions play a vital role in chemistry and biology. The values of standard redox potential (E^(@)) of two half-cells reactions decide which way the reaction is expected to proceed. A simple example is a Daniell cell in which zince goes into solution and copper gets deposited. Given below are set of half-cell reactions (acidic medium ) along with their E^(@) in V with respect to normal hydrogen electrode values. {:(l_(2)+2e^(-)rarr2l^(-),E^(@)=0.54),(Cl_(2)+2e^(-)rarr2Cl^(-)" ",E^(@)=1.36),(Mn^(3+)+e^(-)rarrMn^(2+),E^(2)=1.50),(Fe^(3+)+e^(-)rarrFe^(2+)" ",E^(@)=0.77),(O_(2)+4H^(+)+4e^(-)rarr2H_(2)O,E^(@)=1.23):} while Fe^(3+) is stable, Mn^(3+) is not stable in acid solution because :

Given below are a set of half-cell reactions (acidic medium) along with their E_(@) with respect to normal hydrogen electrode values. Using the data obtain the correct explanation to question given below. {:(I_(2)+2e^(-)rarr2I^(-),E^(@)=0.54),(Cl_(2)+2e^(-)rarr2Cl^(-),E^(@)=1.36),(Mn^(2+)+e^(-)rarrMn^(2+),E^(@)=1.50),(Fe^(3+)+e^(-)rarrFe^(2+),E^(@)=0.77),(O_(2)+4H^(+)+4e^(-)rarr2H_(2)O,E^(@)=1.23):} While Fe^(2+) is stable, Mn^(3+) is not stable in acid solution because:

Standard electrode potential data are useful for understanding the suitability of an oxidant in a redox titration. Some half cell reaction and their standard potentials are given below: MnO_(4)^(-)(aq) +8H^(+)(aq) +5e^(-) rarr Mn^(2+)(aq) +4H_(2)O(l) E^(@) = 1.51V Cr_(2)O_(7)^(2-)(aq) +14H^(+) (aq) +6e^(-) rarr 2Cr^(3+)(aq) +7H_(2)O(l), E^(@) = 1.38V Fe^(3+) (aq) +e^(-) rarr Fe^(2+) (aq), E^(@) = 0.77V CI_(2)(g) +2e^(-) rarr 2CI^(-)(aq), E^(@) = 1.40V Identify the only incorrect statement regarding quantitative estimation of aqueous Fe(NO_(3))_(2)

Standard electrode potential data is given below : Fe^(3+) (aq) + e ^(-) rarr Fe^(2+) (aq) , E^(o) = + 0.77 V Al^(3+) (aq) + 3e^(-) rarr Al (s) , E^(o) = - 1.66 V Br_(2) (aq) + 2e^(-) rarr 2Br^(-) (aq) , E^(o) = +1.08 V Based on the data given above, reducing power of Fe^(2+) Al and Br^(-) will increase in the order :

Given : Co^(3+)+e^(-)rarr Co^(2+), E^(@)=+1.181V Pb^(4+)+2e^(-)rarrPb^(2+),E^(@)=+1.67V Ce^(4+)+e^(-) rarr Ce^(3+), E^(@)=+1.61V Bi^(3+)+3e^(-)rarr Bi^(3+)+3e^(-)rarr Bi, E^(@)=+2.20V Oxidizing power of the species will increase in the order:

DINESH PUBLICATION-ELECTROCHEMISTRY-ADDITIONAL IMPORTANT QUESTIONS
  1. What will happen when chloride is passed through an aqueous solution o...

    Text Solution

    |

  2. What is the souce of electrical energy in a galvanic cell ?

    Text Solution

    |

  3. How can the electrode potentail of an electrode be increased ?

    Text Solution

    |

  4. Knowing that : Cu^(2+)(aq)+2e^(-) to Cu(s), " "E^(@)=+0.34"...

    Text Solution

    |

  5. In an electrochemical cell (Cu-Ag), why are solutions containing Cu^(2...

    Text Solution

    |

  6. What is the difference between cell potential and standard cell potent...

    Text Solution

    |

  7. Write half cell reactions and balanced chemical equations for the foll...

    Text Solution

    |

  8. Write the cell reaction if the Nernst equation is given by the relatio...

    Text Solution

    |

  9. The ionic conductance of alkali metal cations increases with increase ...

    Text Solution

    |

  10. Iron does not rust even if zinc coating on its surface is broken but t...

    Text Solution

    |

  11. Rusting of iron becomes quicker in saline medium. Explain.

    Text Solution

    |

  12. Why molbilities of H^(o+) ions in ice is greater as compared to liquid...

    Text Solution

    |

  13. Given that, Co^(3+) +e^(-)rarr Co^(2+) E^(@) = +1.82 V 2H(2)O rarr O...

    Text Solution

    |

  14. What would happen if the protective tin coating over an iron bucket i...

    Text Solution

    |

  15. Explain why zinc dissolves in dilute HCl to liberate H(2)(g) but from ...

    Text Solution

    |

  16. There iron sheets have been coated separately with three metals (A,B a...

    Text Solution

    |

  17. Why cannot aluminium metal be produced by the electrolysis of aqueous ...

    Text Solution

    |

  18. Tarnished silver contains Ag2S. Can this tarnish be removed by placing...

    Text Solution

    |

  19. The following chemical reaction occurring in an electrochemical cell :...

    Text Solution

    |

  20. An electrochemical cell stops working after sometime. Explain.

    Text Solution

    |