Home
Class 12
CHEMISTRY
Calculate the potential of the following...

Calculate the potential of the following cell reaction at 298 K
`Sn^(4+)(1.50 M)+Zn(s) to Sn^(2+)(0.50 M)+Zn^(2+)(2.0 M)`
The standard potential, `E^(@)` of the cell is 0.89 V. Whether the potential of the cell will increase or decrease if the concentration of `Sn^(4+)` is increased in the cell.

Text Solution

AI Generated Solution

The correct Answer is:
To calculate the potential of the given cell reaction at 298 K, we can use the Nernst equation. The Nernst equation relates the cell potential under non-standard conditions to the standard cell potential and the concentrations of the reactants and products. ### Step-by-Step Solution: 1. **Identify the given values**: - Standard cell potential, \( E^\circ_{\text{cell}} = 0.89 \, \text{V} \) - Concentration of \( \text{Sn}^{4+} = 1.50 \, \text{M} \) - Concentration of \( \text{Sn}^{2+} = 0.50 \, \text{M} \) - Concentration of \( \text{Zn}^{2+} = 2.0 \, \text{M} \) - The number of electrons transferred, \( n = 2 \) 2. **Write the Nernst equation**: \[ E_{\text{cell}} = E^\circ_{\text{cell}} - \frac{0.0591}{n} \log \left( \frac{[\text{Sn}^{2+}]}{[\text{Sn}^{4+}]} \cdot \frac{1}{[\text{Zn}^{2+}]} \right) \] 3. **Substitute the values into the Nernst equation**: \[ E_{\text{cell}} = 0.89 \, \text{V} - \frac{0.0591}{2} \log \left( \frac{0.50}{1.50} \cdot \frac{1}{2.0} \right) \] 4. **Calculate the logarithmic term**: \[ \frac{0.50}{1.50} \cdot \frac{1}{2.0} = \frac{0.50}{3.0} = \frac{1}{6} \approx 0.1667 \] \[ \log(0.1667) \approx -0.778 \] 5. **Substitute the logarithm back into the equation**: \[ E_{\text{cell}} = 0.89 \, \text{V} - \frac{0.0591}{2} \cdot (-0.778) \] \[ E_{\text{cell}} = 0.89 \, \text{V} + 0.0229 \cdot 0.778 \] \[ E_{\text{cell}} = 0.89 \, \text{V} + 0.0178 \, \text{V} \] \[ E_{\text{cell}} \approx 0.9078 \, \text{V} \] 6. **Determine the effect of increasing the concentration of \( \text{Sn}^{4+} \)**: - If the concentration of \( \text{Sn}^{4+} \) is increased, the term \(\frac{[\text{Sn}^{2+}]}{[\text{Sn}^{4+}]}\) in the logarithm will decrease, leading to a decrease in the logarithmic value. - Since the logarithm is negative, a decrease in this value will result in an increase in the overall cell potential \( E_{\text{cell}} \). ### Final Answer: The potential of the cell reaction at 298 K is approximately **0.9078 V**. Increasing the concentration of \( \text{Sn}^{4+} \) will **increase the potential of the cell**.

To calculate the potential of the given cell reaction at 298 K, we can use the Nernst equation. The Nernst equation relates the cell potential under non-standard conditions to the standard cell potential and the concentrations of the reactants and products. ### Step-by-Step Solution: 1. **Identify the given values**: - Standard cell potential, \( E^\circ_{\text{cell}} = 0.89 \, \text{V} \) - Concentration of \( \text{Sn}^{4+} = 1.50 \, \text{M} \) - Concentration of \( \text{Sn}^{2+} = 0.50 \, \text{M} \) ...
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    DINESH PUBLICATION|Exercise ADDITIONAL NUMERICAL PROBLEMS FOR PRACTICE|12 Videos
  • ELECTROCHEMISTRY

    DINESH PUBLICATION|Exercise HOTS|17 Videos
  • D-AND -F BLOCK ELEMENTS

    DINESH PUBLICATION|Exercise BRAIN STORMING MULTIPLE CHOICE QUESTIONS (MCQS)|13 Videos
  • ETHERS

    DINESH PUBLICATION|Exercise (MCQs)|8 Videos

Similar Questions

Explore conceptually related problems

Write the Nernst equation and calculate e.m.f. of the following cell at 298 K : Sn (s) |Sn^(2+) (0.050 M) ||H^(+) (0.20 M) |H_(2) (1 atm) |Pt.

Calculate EMF of following cell at 298 K Zn|ZnSO_(4) (0.1 M) ||CuSO_(4) (1.0 M)|Cu (s) if E_(cell) = 2.0 V

Calculate the potential of the following cell Sn^(4+)(1.5M)+ZnrarrSn^(2+)(0.5M)+zn^(2+)(2M) . "Given : "E_(Sn^(4+)//Sn^(2+))^(@)0.13V, E_(Zn^(2+)//Zn)^(@)=-0.76V Will the cell potential uarr or darr if the concentration of Sn4+ is increased ?

Calculate the half-cell potential at 298 K for the reaction, Zn^(2+)+2e^(-) rarr Zn If [Zn^(2+)]=0.1 M and E^(@)=-0.76 volt.

DINESH PUBLICATION-ELECTROCHEMISTRY-PROBLEMS FOR PRACTIVE
  1. Calculate the emf for the following cell at 298 K. Cd//Cd^(2+)(0.1 M...

    Text Solution

    |

  2. Standard electrode potentials are given as, E(Cu^(2+)//Cd)^(@)=0.34"...

    Text Solution

    |

  3. Calculate the potential of the following cell reaction at 298 K Sn^(...

    Text Solution

    |

  4. A voltaic cell is set up at 25^(@)Cwith the following half cells : A...

    Text Solution

    |

  5. At what concetration of Ag^(2+) ions, will the electrode have a potent...

    Text Solution

    |

  6. At what pH of HCl solution, will hydrogen gas electrode show electrode...

    Text Solution

    |

  7. Calculate the emf of the following cell at 25^(@)C. Zn|Zn^(2+)(0.001...

    Text Solution

    |

  8. Given that E^(@)(Zn^(2+)//Zn)=0.76V, E^(@)(H^(+)//H(2))=0.00" V ". Wha...

    Text Solution

    |

  9. Calculate e.m.f. of the following cell at 298 K, 2Cr(s)+3Fe^(2+)(0.1...

    Text Solution

    |

  10. Calculate the following cell reaction cell at 298 K. 2Ag^(+)+Cd to 2...

    Text Solution

    |

  11. Calculate emf of the following cell reaction at 2968 K : Ni(s)//Ni^(...

    Text Solution

    |

  12. Calculate equilibrium constant for the reaction at 25^(@)C Cu(s)+2Ag...

    Text Solution

    |

  13. Calculate equilibrium constant for the reaction : Mg(s) |Mg^(2+)(0.0...

    Text Solution

    |

  14. Calculate the value of equilibrium constant for the reaction : 2Fe^...

    Text Solution

    |

  15. Calculate equilibrium constant for the reaction : Zn+Cd^(2+) hArr Zn...

    Text Solution

    |

  16. Calculate the standard free energy change for the reaction : Zn(s)|Z...

    Text Solution

    |

  17. Calculate the maximum possible electrical work that can be obtined fro...

    Text Solution

    |

  18. The value of DeltaG^(@) in the Daniell cell has been found to be -212....

    Text Solution

    |

  19. For the equilibrium reaction: 2H(2)(g) +O(2)(g) hArr 2H(2)O(l) at 29...

    Text Solution

    |

  20. Calculate Delta(r)G^(@) for the reaction : Mg(s)+Cu^(2+)(aq) to Mg^(...

    Text Solution

    |