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The standard heat of combustion of a sol...

The standard heat of combustion of a solid boron is equal to:

A

`DeltaH_(f)^(@)(B_(2)O_(3))`

B

`1//2DeltaH_(f)^(@)(B_(2)O_(3))`

C

`2DeltaH_(f)^(@)(B_(2)O_(3))`

D

`1//2DeltaH_(f)^(@)(B_(2)O_(3))`

Text Solution

Verified by Experts

The correct Answer is:
B

Combustion reaction of solid boron
`B(s)+(3)/(4)O_(2)(g)rarr(1)/(2)B_(2)O_(3)(s)`
`Delta H_(r )^(o)=Delta H_(c )^(o)=(1)/(2)DeltaH_(f)^(o)(B_(2)O_(3),s)-Delta H_(f)^(o)(B,s)-(3)/(4)Delta H_(f)^(o)(O_(2),g)`
`Delta H_(f)^(o)` of element in stable state of aggregation is assumed to be zero.
`DeltaH_(c )^(@)=(1)/(2)Delta H_(f)^(o)(B_(2)O_(3),s)`
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