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Caesium chlorides is formed according to...

Caesium chlorides is formed according to the following equation `Cs(s)+0.5Cl_(2)(g)rarrCaCl(s)`. The enthalpy of sublimation of Cs, enthalpy of dissocitation of chlorine, ionization energy of Cs and electron affinity of chlorine are 81.2,243.0,375.7 and -348.3 kJ`mol^(-1)`. The energy change involved in the formation of CsCl is -388.6 kJ `mol^(-)`. Calculate the lattice energy of CsCl.

A

618.7 kJ `mol^(-1)`

B

1237.4 kJ `mol^(-1)`

C

`1237.4 kJ mol^(-1)`

D

`-532.7 KJ mol^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
D

`-12250x - 13000(1-x)= -12500`
`750xx500 rArr x=2//3`
So , required ratio is =`(2)/(1)`
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