Home
Class 11
CHEMISTRY
The central atom of which of the followi...

The central atom of which of the following compounds has four bond pairs and two lone pair

A

`SF_4`

B

`XeF_4`

C

`NH_4^(+)`

D

`SF_6`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the central atom of which compound has four bond pairs and two lone pairs, we will analyze each option step by step. ### Step 1: Analyze Option 1 - SF4 1. **Identify the central atom**: In SF4, the central atom is Sulfur (S). 2. **Count valence electrons**: Sulfur has 6 valence electrons, and each Fluorine (F) has 7 valence electrons. Thus, the total number of valence electrons is: - Sulfur: 6 - 4 Fluorines: 4 × 7 = 28 - Total = 6 + 28 = 34 valence electrons. 3. **Draw the Lewis structure**: Connect the 4 Fluorine atoms to Sulfur with single bonds. This uses 8 electrons (4 bonds). 4. **Distribute remaining electrons**: After forming bonds, 26 electrons remain. Each Fluorine needs 6 more electrons to complete their octet (24 electrons total), leaving 2 electrons. 5. **Count bond pairs and lone pairs**: - Bond pairs: 4 (from the S-F bonds) - Lone pairs: 1 (the 2 remaining electrons form 1 lone pair) 6. **Conclusion**: SF4 has 4 bond pairs and 1 lone pair. **Not the answer.** ### Step 2: Analyze Option 2 - XeF4 1. **Identify the central atom**: In XeF4, the central atom is Xenon (Xe). 2. **Count valence electrons**: Xenon has 8 valence electrons, and each Fluorine has 7 valence electrons. Thus, the total number of valence electrons is: - Xenon: 8 - 4 Fluorines: 4 × 7 = 28 - Total = 8 + 28 = 36 valence electrons. 3. **Draw the Lewis structure**: Connect the 4 Fluorine atoms to Xenon with single bonds. This uses 8 electrons (4 bonds). 4. **Distribute remaining electrons**: After forming bonds, 28 electrons remain. Each Fluorine needs 6 more electrons to complete their octet (24 electrons total), leaving 4 electrons. 5. **Count bond pairs and lone pairs**: - Bond pairs: 4 (from the Xe-F bonds) - Lone pairs: 2 (the 4 remaining electrons form 2 lone pairs) 6. **Conclusion**: XeF4 has 4 bond pairs and 2 lone pairs. **This is the answer.** ### Step 3: Analyze Option 3 - NH4+ 1. **Identify the central atom**: In NH4+, the central atom is Nitrogen (N). 2. **Count valence electrons**: Nitrogen has 5 valence electrons, and each Hydrogen has 1 valence electron. Thus, the total number of valence electrons is: - Nitrogen: 5 - 4 Hydrogens: 4 × 1 = 4 - Total = 5 + 4 = 9 valence electrons (but we subtract 1 for the positive charge). 3. **Draw the Lewis structure**: Connect the 4 Hydrogen atoms to Nitrogen with single bonds. This uses 4 electrons (4 bonds). 4. **Distribute remaining electrons**: After forming bonds, 5 electrons remain. 5. **Count bond pairs and lone pairs**: - Bond pairs: 4 (from the N-H bonds) - Lone pairs: 0 (no remaining electrons) 6. **Conclusion**: NH4+ has 4 bond pairs and 0 lone pairs. **Not the answer.** ### Step 4: Analyze Option 4 - SF6 1. **Identify the central atom**: In SF6, the central atom is Sulfur (S). 2. **Count valence electrons**: Sulfur has 6 valence electrons, and each Fluorine has 7 valence electrons. Thus, the total number of valence electrons is: - Sulfur: 6 - 6 Fluorines: 6 × 7 = 42 - Total = 6 + 42 = 48 valence electrons. 3. **Draw the Lewis structure**: Connect the 6 Fluorine atoms to Sulfur with single bonds. This uses 12 electrons (6 bonds). 4. **Distribute remaining electrons**: After forming bonds, 36 electrons remain. Each Fluorine needs 6 more electrons to complete their octet (36 electrons total), leaving 0 electrons. 5. **Count bond pairs and lone pairs**: - Bond pairs: 6 (from the S-F bonds) - Lone pairs: 0 (no remaining electrons) 6. **Conclusion**: SF6 has 6 bond pairs and 0 lone pairs. **Not the answer.** ### Final Answer The compound with a central atom that has 4 bond pairs and 2 lone pairs is **XeF4** (Option 2). ---
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    NARAYNA|Exercise CUQ (INTERODUCTION, VALENCE AND FORMULA WRITING)|4 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    NARAYNA|Exercise CUQ (KOSSEL LEWIS THRORY)|16 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    NARAYNA|Exercise EVALUATE YOUR SELF - 2|6 Videos
  • CARBONYL COMPOUNDS

    NARAYNA|Exercise LEVEL -VI|99 Videos
  • CHEMICAL EQUILIBRIUM

    NARAYNA|Exercise Exercise -IV|33 Videos

Similar Questions

Explore conceptually related problems

Which of the following molcules have three lone pairs around central atom -

Which of the following molecules has one lone pair of electrons on the central atom

The shape of a molecule which has 3 bond paires and one lone pair is :

In which of the following, the central atoms has two lone pairs of electrons

In which of the following cases the number of lone pairs on central atom is two?

In which of the following , central atom does not have one lone pairs of electron ?

Which of the following species contains three bond pairs and two ione pair around the central atom ?

In which of the following compounds is there the least delocalization of the lone pair of electrons on the nitrogen atom?