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Which of the following molecules has tri...

Which of the following molecules has trigonal planar geometry ?

A

`BF_3`

B

`NH_3`

C

`H_2O`

D

`IF_3`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given molecules has a trigonal planar geometry, we will analyze each option step by step. ### Step 1: Analyze BF3 1. **Identify the central atom**: In BF3, the central atom is boron (B). 2. **Count valence electrons**: Boron has 3 valence electrons. 3. **Draw the structure**: Boron is bonded to three fluorine (F) atoms with single bonds. 4. **Calculate steric number**: - Number of sigma bonds = 3 (one bond with each fluorine) - Number of lone pairs = 0 (boron has no lone pairs) - Steric number = 3 + 0 = 3 5. **Determine hybridization**: - With a steric number of 3, the hybridization is sp². 6. **Determine geometry**: - The geometry corresponding to sp² hybridization is trigonal planar. ### Step 2: Analyze NH3 1. **Identify the central atom**: In NH3, the central atom is nitrogen (N). 2. **Count valence electrons**: Nitrogen has 5 valence electrons. 3. **Draw the structure**: Nitrogen is bonded to three hydrogen (H) atoms with single bonds and has one lone pair. 4. **Calculate steric number**: - Number of sigma bonds = 3 (one bond with each hydrogen) - Number of lone pairs = 1 - Steric number = 3 + 1 = 4 5. **Determine hybridization**: - With a steric number of 4, the hybridization is sp³. 6. **Determine geometry**: - The geometry corresponding to sp³ hybridization is tetrahedral. ### Step 3: Analyze H2O 1. **Identify the central atom**: In H2O, the central atom is oxygen (O). 2. **Count valence electrons**: Oxygen has 6 valence electrons. 3. **Draw the structure**: Oxygen is bonded to two hydrogen atoms with single bonds and has two lone pairs. 4. **Calculate steric number**: - Number of sigma bonds = 2 (one bond with each hydrogen) - Number of lone pairs = 2 - Steric number = 2 + 2 = 4 5. **Determine hybridization**: - With a steric number of 4, the hybridization is sp³. 6. **Determine geometry**: - The geometry corresponding to sp³ hybridization is also tetrahedral. ### Step 4: Analyze IF3 1. **Identify the central atom**: In IF3, the central atom is iodine (I). 2. **Count valence electrons**: Iodine has 7 valence electrons. 3. **Draw the structure**: Iodine is bonded to three fluorine atoms with single bonds and has two lone pairs. 4. **Calculate steric number**: - Number of sigma bonds = 3 (one bond with each fluorine) - Number of lone pairs = 2 - Steric number = 3 + 2 = 5 5. **Determine hybridization**: - With a steric number of 5, the hybridization is sp³d. 6. **Determine geometry**: - The geometry corresponding to sp³d hybridization is trigonal bipyramidal. ### Conclusion Based on the analysis: - **BF3** has a trigonal planar geometry. - **NH3** has a tetrahedral geometry. - **H2O** has a tetrahedral geometry. - **IF3** has a trigonal bipyramidal geometry. Thus, the molecule with trigonal planar geometry is **BF3**.
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