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For which of the following hybridisation...

For which of the following hybridisation the bond angle is maximum

A

`sp^2`

B

sp

C

`sp^3`

D

`dsp^2`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which hybridization has the maximum bond angle, we need to analyze the percentage of s character in each hybridization type. The bond angle is directly proportional to the percentage of s character; the higher the s character, the larger the bond angle. ### Step-by-Step Solution: 1. **Identify the Hybridization Types**: The given hybridizations are sp, sp2, sp3, and dsp2. 2. **Calculate the Percentage of s Character for Each Hybridization**: - **For sp2 Hybridization**: - In sp2, there is 1 s orbital and 2 p orbitals. - Total orbitals = 1 (s) + 2 (p) = 3 - Percentage of s character = (1/3) × 100 = 33.33% - **For sp Hybridization**: - In sp, there is 1 s orbital and 1 p orbital. - Total orbitals = 1 (s) + 1 (p) = 2 - Percentage of s character = (1/2) × 100 = 50% - **For sp3 Hybridization**: - In sp3, there is 1 s orbital and 3 p orbitals. - Total orbitals = 1 (s) + 3 (p) = 4 - Percentage of s character = (1/4) × 100 = 25% - **For dsp2 Hybridization**: - In dsp2, there is 1 s orbital, 1 d orbital, and 2 p orbitals. - Total orbitals = 1 (s) + 1 (d) + 2 (p) = 4 - Percentage of s character = (1/4) × 100 = 25% 3. **Compare the Percentages of s Character**: - sp2: 33.33% - sp: 50% - sp3: 25% - dsp2: 25% 4. **Determine the Maximum Bond Angle**: - Since the bond angle is directly proportional to the percentage of s character, the hybridization with the highest s character will have the maximum bond angle. - The maximum s character is found in sp hybridization (50%). 5. **Conclusion**: Therefore, the hybridization with the maximum bond angle is **sp**. ### Final Answer: The hybridization with the maximum bond angle is **sp**.
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