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How much PCl(5) must be added to a one l...

How much `PCl_(5)` must be added to a one little vessel at `250^(@)C` in order to obtain a concentration of 0.1 mole of `Cl_(2)` at equilibrium. `K_(c)` for `PCl_5(g)hArrPCl_(3)(g)+Cl_(2)(g)` is `0.0414`

A

3.415 mole

B

34.15 mole

C

0.03415 mole

D

0.3415 mole

Text Solution

Verified by Experts

The correct Answer is:
D

`PCl_(5) Leftrightarrow PCl_(3)+CI_(2)`
`{:(,"initial",a,0,0),(,eq:, (a-0.1),0.1,0.1):}`
`K_(c)=((0.1)/(1) xx (0.1))/(1))/((a-0.1)/(1)),` a=0.3415 mole
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Amount of PCl_(5) (in moles) need to be added to one litre vessel at 250^(@)C in order to obtain a concentration of 0.1 "mole" of Cl_(2) for the given change is: PCl_(5)hArrPCl_(3)+Cl_(2) , K_(c)=0.0414 mol litre^(-1)

For the reaction, PCl_(5)(g)to PCl_(3)(g)+Cl_(2)(g)

For PCl_(5)(g)hArrPCl_(3)(g)+Cl_(2)(g), write the expression of K_(c)

0.1 mol of PCl_(5) is vaporised in a litre vessel at 260^(@)C . Calculate the concentration of Cl_(2) at equilibrium, if the equilibrium constant for the dissociation of PCl_(5) is 0.0414 .

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