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Which of the following statements is inc...

Which of the following statements is incorrect

A

In equilibrium mixture office and water kept in perfectly insulated flask mass ofice and water does not change with time.

B

The intensity of red colour increases when oxalic acid is added to a solution containing iron (III) nitrate and potassium thiocyanate.

C

On addition of catalyst the equilibrium constant value is not affected.

D

Equilibrium constant for a reaction with negative `triangleH` value decreases as the temperature increases.

Text Solution

Verified by Experts

The correct Answer is:
B

In the reaction `Fe^(3+)+SCN^(-) Leftrightarrow FeSCN^(2+)`
When oxalic acid is added it combines with `Fe^(3+)` ions, then, equilibrium shifts towards backward direction and intensity of red colour decreases.
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NARAYNA-CHEMICAL EQUILIBRIUM-Exercise -IV
  1. Which of the following is not a general characteristic of equilibrium ...

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  2. PCI(5), PCI(3) and CI(2) are in equilibrium at 500 K in a closed cont...

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  3. Which of the following statements is incorrect

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  4. When hydrochloric aicd is addded to cobalt and nitrate solution at roo...

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  5. Which of the following options will be correct for the stage of half c...

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  6. What will be the correct order of vapour pressure of water, acetone an...

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  7. At 500 K, equlibrium constant, K(c) for the following reaction is 5. ...

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  8. On increasing the pressure, in which dirction will the gas phase react...

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  9. In which of the following reactions, the equilibrium reamins unaffecte...

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  10. For the reaction N(2)O(4)(g)hArr2NO(2)(g), the value of K is 50 at 400...

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  11. The value of K(c) for the reaction 2HI(g)hArrH(2)+I(2)(g) is 1xx10^(-4...

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  12. For a reaction, CaCO(3(s)) rarr CaO((s))+CO(2(g)) Delta(f)H^(@)(Ca...

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  13. Reaction 2BaO(2)(s)hArr2BaO(s) + O(2)(g), Delta H = +ve. At equilibriu...

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  14. The reaction quotient (Q) for the reaction N(2)(g) + 3H(2)(g)hArr2NH(3...

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  15. Equilibrium constants K(1) and K(2) for the following equilibria NO(...

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  16. For the reaction CH(4)(g)+2O(2)(g)hArr CO(2)(g)+2H(2)O(I) Delta(r)...

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  17. The following equilibria are given by : N(2)+3H(2) hArr 2NH(3), K(1)...

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  18. The dissociation equilibrium of a gas AB, can be represented as The d...

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  19. If the concentration of OH^(-) ions in the reaction Fe(OH)(3)(s)hArr...

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  20. the value of equilibrium constant for the reaction HI(g) hArr 1//2 ...

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