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2 - Butyne which treated with lithium in...

2 - Butyne which treated with lithium in presence of liquid ammonia gives

A

cis -2- butene

B

trans -2- butene

C

n - butane

D

1 -butyne

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The correct Answer is:
To solve the question of what 2-butyne gives when treated with lithium in the presence of liquid ammonia, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Compound**: - We start with 2-butyne, which is a terminal alkyne with the structure: \[ CH_3-C \equiv C-CH_3 \] - This compound has a triple bond between the second and third carbon atoms. 2. **Understand the Reaction Conditions**: - The reaction involves lithium in liquid ammonia. This combination is known for performing Birch Reduction, which is a method to reduce alkynes to alkenes. 3. **Apply Birch Reduction**: - In Birch Reduction, the alkyne is partially reduced to form a conjugated diene. The reduction typically leads to the formation of a mixture of cis and trans isomers of the alkene. - For 2-butyne, the reduction will yield 2-butene. 4. **Determine the Products**: - The product of the Birch Reduction of 2-butyne will be a mixture of cis-2-butene and trans-2-butene. - Thus, the final products are: - **cis-2-butene** - **trans-2-butene** ### Final Answer: When 2-butyne is treated with lithium in the presence of liquid ammonia, it gives a mixture of cis-2-butene and trans-2-butene. ---
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