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H-C-=C-H+ 2NaNH(2)rarr Aoverset("2 mole"...

`H-C-=C-H+ 2NaNH_(2)rarr Aoverset("2 mole")underset(CH_(3)Cl)rarrB`
then 'B' is

A

1 - Butyne

B

2 - Butyne

C

2 - Pentyne

D

Propyne

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AI Generated Solution

The correct Answer is:
To solve the given question step by step, we will analyze the reactions taking place and determine the final product 'B'. ### Step 1: Identify the starting compound The starting compound is **H-C≡C-H**, which is ethyne (acetylene). ### Step 2: Reaction with NaNH₂ When ethyne reacts with **2 moles of NaNH₂**, the sodium amide (NaNH₂) acts as a strong base. It abstracts a proton (H⁺) from the terminal carbon of ethyne, resulting in the formation of a carbanion (negatively charged carbon). The reaction can be represented as: \[ \text{H-C≡C-H} + \text{NaNH}_2 \rightarrow \text{H-C≡C}^- \text{Na}^+ + \text{NH}_3 \] ### Step 3: Formation of the carbanion The carbanion formed is **H-C≡C⁻**. The negative charge on the carbon is stabilized due to its sp hybridization. ### Step 4: Reaction with CH₃Cl Next, the carbanion reacts with **2 moles of CH₃Cl**. The carbanion acts as a nucleophile and attacks the electrophilic carbon in CH₃Cl, displacing the chloride ion (Cl⁻). The reaction can be represented as: \[ \text{H-C≡C}^- + \text{CH}_3\text{Cl} \rightarrow \text{H-C≡C-CH}_3 + \text{Cl}^- \] ### Step 5: Repeat the reaction Since we have 2 moles of NaNH₂ and CH₃Cl, we can repeat the above reaction. The carbanion formed in the previous step can again react with another mole of CH₃Cl. The second reaction is: \[ \text{H-C≡C-CH}_3 + \text{CH}_3\text{Cl} \rightarrow \text{CH}_3\text{C≡C-CH}_3 + \text{Cl}^- \] ### Step 6: Final product After both reactions, the final product 'B' is **CH₃C≡CCH₃**, which is **2-butyne**. ### Conclusion Thus, the final product 'B' is **2-butyne**. ---

To solve the given question step by step, we will analyze the reactions taking place and determine the final product 'B'. ### Step 1: Identify the starting compound The starting compound is **H-C≡C-H**, which is ethyne (acetylene). ### Step 2: Reaction with NaNH₂ When ethyne reacts with **2 moles of NaNH₂**, the sodium amide (NaNH₂) acts as a strong base. It abstracts a proton (H⁺) from the terminal carbon of ethyne, resulting in the formation of a carbanion (negatively charged carbon). ...
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NARAYNA-HYDROCARBONS -EXERCISE - 2 (H.W) (PROPERTIES OF ALKENES)
  1. underset(Cl)underset(|)(C)H(2)-underset(Cl)underset(|)(C)H(2)overset(A...

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  2. CH-=Choverset(HCl)toAoverset("Polymerisation")toB The polymer B is

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  3. H-C-=C-H+ 2NaNH(2)rarr Aoverset("2 mole")underset(CH(3)Cl)rarrB then...

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  4. When 2-pentyn is treated with dilute H(2)SO(4) and HgSO(4) the product...

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  5. The cyclic polymerisation of methyl acetylene produces

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  6. The compounds 1-butyne and 2-butyne can be distinguished by using

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  7. Which of the following orders regarding acidic strength is correct

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  8. Anunknown compound 'A' has a molecular formula of C(4)H(6) when 'A' is...

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  9. The reduction of 4 - octyne with H(2) in the presence of Pd //CaCo3 qu...

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  10. The hydrolysis of Mg(2)C(3) produces

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  11. Pure acetylene has sweet smell, where as impure gives garlic occur du...

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  12. The stronger base is

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  13. The colour of the precipitate formed when acetylene is passed through ...

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  14. What is the product when acetylene reacts with HCN

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  15. Westron is the solvent obtained by the reaction of chlorine with

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  16. The final product formed when ethyne and acetic acid react is

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  17. A compound (C(5)H(8)) reacts with ammoniacal AgNO(3) to give a white p...

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  18. 1-butyne on reaction with hot alkaline KMnO(4) gives:

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  19. Order of acidity of H(2)O, NH(3) and acetylene is :

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  20. Which of the following is expected to aromatic

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