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The reduction of 4 - octyne with H(2) in...

The reduction of 4 - octyne with `H_(2)` in the presence of `Pd //CaCo_3` quinoline gives

A

Trans -4- octene

B

cis -4- octene

C

A mixture of cis and trans -4 octene

D

A completely reduced productc `C_(8)H_(18)`

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The correct Answer is:
To solve the question regarding the reduction of 4-octyne with hydrogen in the presence of Pd/CaCO3 and quinoline, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Compound**: - The compound we are starting with is 4-octyne, which is an alkyne with the structure: \[ CH_3-CH_2-C≡C-CH_2-CH_2-CH_2-CH_3 \] 2. **Understand the Reaction Conditions**: - The reduction is carried out using hydrogen gas (H2) in the presence of palladium on calcium carbonate (Pd/CaCO3) and quinoline. - Pd/CaCO3 is a catalyst that promotes the hydrogenation of alkynes. 3. **Determine the Type of Reduction**: - The catalyst used (Pd/CaCO3) is known to selectively produce the cis isomer when reducing alkynes. - This is because the catalyst allows for the addition of hydrogen to occur in a syn fashion, leading to the formation of the cis isomer. 4. **Perform the Reduction**: - When 4-octyne undergoes hydrogenation, it will be converted to a corresponding alkene. - Specifically, the reduction of 4-octyne will yield cis-4-octene: \[ CH_3-CH_2-CH=CH-CH_2-CH_2-CH_2-CH_3 \quad \text{(cis-4-octene)} \] 5. **Final Product Identification**: - The final product of this reaction is therefore cis-4-octene. ### Conclusion: The reduction of 4-octyne with H2 in the presence of Pd/CaCO3 and quinoline gives **cis-4-octene**.

To solve the question regarding the reduction of 4-octyne with hydrogen in the presence of Pd/CaCO3 and quinoline, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Compound**: - The compound we are starting with is 4-octyne, which is an alkyne with the structure: \[ CH_3-CH_2-C≡C-CH_2-CH_2-CH_2-CH_3 ...
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NARAYNA-HYDROCARBONS -EXERCISE - 2 (H.W) (PROPERTIES OF ALKENES)
  1. Which of the following orders regarding acidic strength is correct

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  2. Anunknown compound 'A' has a molecular formula of C(4)H(6) when 'A' is...

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  3. The reduction of 4 - octyne with H(2) in the presence of Pd //CaCo3 qu...

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  4. The hydrolysis of Mg(2)C(3) produces

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  5. Pure acetylene has sweet smell, where as impure gives garlic occur du...

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  6. The stronger base is

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  7. The colour of the precipitate formed when acetylene is passed through ...

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  8. What is the product when acetylene reacts with HCN

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  9. Westron is the solvent obtained by the reaction of chlorine with

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  10. The final product formed when ethyne and acetic acid react is

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  11. A compound (C(5)H(8)) reacts with ammoniacal AgNO(3) to give a white p...

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  12. 1-butyne on reaction with hot alkaline KMnO(4) gives:

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  13. Order of acidity of H(2)O, NH(3) and acetylene is :

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  14. Which of the following is expected to aromatic

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  15. Which of the following carbocation is expected to be least stable

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  16. Which of the following carbocations is expected to be most stable ?

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  17. Which of the following structure will not have 4pi electrons

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  18. CaC(2)overset(H(2)O)toAoverset("Red tube hot")toBunderset(CH(3)Cl)over...

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  19. C(2)H(2)overset("Red hot tube")toAoverset("fuming "H(2)SO(4))toB then ...

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  20. Aoverset("soda lime")toC(6)H(6)overset(Cl(2),hv)toB, In this reaction ...

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