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Two elements X and Y have atomic number ...

Two elements X and Y have atomic number 15 and a respectively. The ratio of wavelength of `K_alpha` X-rays emitted by both is 1:4. Find the value of a

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To solve the problem, we need to find the atomic number \( a \) of element Y, given that the atomic number of element X is 15 and the ratio of the wavelengths of K-alpha X-rays emitted by both elements is 1:4. ### Step-by-step Solution: 1. **Understanding the relationship**: According to Moseley's law, the frequency \( \nu \) of the X-rays is related to the atomic number \( Z \) by the formula: \[ \nu \propto (Z - b)^2 \] where \( b \) is the screening constant. For K-alpha lines, \( b = 1 \). 2. **Expressing frequency in terms of wavelength**: The frequency is inversely proportional to the wavelength \( \lambda \): \[ \nu \propto \frac{1}{\lambda} \] Therefore, we can write: \[ \lambda \propto \frac{1}{(Z - 1)^2} \] 3. **Setting up the ratio**: Given the ratio of the wavelengths of X-rays emitted by elements X and Y is \( \frac{\lambda_X}{\lambda_Y} = \frac{1}{4} \), we can express this in terms of their atomic numbers: \[ \frac{\lambda_X}{\lambda_Y} = \frac{(Z_Y - 1)^2}{(Z_X - 1)^2} \] Substituting \( Z_X = 15 \) and \( Z_Y = a \): \[ \frac{(a - 1)^2}{(15 - 1)^2} = \frac{1}{4} \] 4. **Calculating the squares**: Simplifying the equation: \[ \frac{(a - 1)^2}{14^2} = \frac{1}{4} \] This implies: \[ (a - 1)^2 = \frac{14^2}{4} \] \[ (a - 1)^2 = \frac{196}{4} = 49 \] 5. **Taking the square root**: Taking the square root of both sides gives: \[ a - 1 = \pm 7 \] This results in two possible equations: - \( a - 1 = 7 \) → \( a = 8 \) - \( a - 1 = -7 \) → \( a = -6 \) (not a valid atomic number) 6. **Final answer**: Therefore, the only valid solution is: \[ a = 8 \] ### Conclusion: The value of \( a \) is \( 8 \).

To solve the problem, we need to find the atomic number \( a \) of element Y, given that the atomic number of element X is 15 and the ratio of the wavelengths of K-alpha X-rays emitted by both elements is 1:4. ### Step-by-step Solution: 1. **Understanding the relationship**: According to Moseley's law, the frequency \( \nu \) of the X-rays is related to the atomic number \( Z \) by the formula: \[ \nu \propto (Z - b)^2 \] ...
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