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The reaction quotient, 'Qc' in useful in...

The reaction quotient, `'Q_c'` in useful in predicting the direction of the reaction. Which of the following is incorrect?

A

If `Q_c gt K_c` , the reverse reaction is favoured

B

If `Q_c lt K_c`, the forward reaction is favoured

C

If `Q_c gt K_c` , forward reaction is favoured.

D

If `Q_c = K_c`, reaction at equillibirium.

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The correct Answer is:
To solve the question regarding the reaction quotient \( Q_c \) and its role in predicting the direction of a chemical reaction, we will analyze the definitions and implications of \( Q_c \) in relation to the equilibrium constant \( K_c \). ### Step-by-Step Solution: 1. **Understanding \( Q_c \)**: - The reaction quotient \( Q_c \) is defined as the ratio of the concentrations (or partial pressures) of the products to the reactants at any point in time, not necessarily at equilibrium. - For a general reaction: \[ aA + bB \rightleftharpoons cC + dD \] The expression for \( Q_c \) is: \[ Q_c = \frac{[C]^c[D]^d}{[A]^a[B]^b} \] 2. **Comparing \( Q_c \) and \( K_c \)**: - The equilibrium constant \( K_c \) is the value of \( Q_c \) when the reaction has reached equilibrium. - The relationship between \( Q_c \) and \( K_c \) helps in predicting the direction of the reaction: - If \( Q_c < K_c \): The reaction will proceed in the forward direction (towards products) to reach equilibrium. - If \( Q_c > K_c \): The reaction will proceed in the reverse direction (towards reactants) to reach equilibrium. - If \( Q_c = K_c \): The system is at equilibrium, and no net change will occur. 3. **Evaluating the Options**: - We need to determine which of the statements regarding \( Q_c \) and \( K_c \) is incorrect based on the above understanding. - The options likely state various scenarios about the relationship between \( Q_c \) and \( K_c \) and the direction of the reaction. 4. **Identifying the Incorrect Statement**: - By analyzing the possible statements: - If \( Q_c < K_c \): The reaction goes forward (correct). - If \( Q_c > K_c \): The reaction goes backward (correct). - If \( Q_c = K_c \): The reaction is at equilibrium (correct). - Any statement that contradicts these relationships would be incorrect. 5. **Conclusion**: - After evaluating the options, the statement that does not align with the principles of \( Q_c \) and \( K_c \) will be identified as the incorrect one.
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