Home
Class 11
CHEMISTRY
Consider the reactions: a. H(3)PO(2)(a...

Consider the reactions:
a. `H_(3)PO_(2)(aq)+4AgNO_(3)(aq)+2H_(2)O(l) rarr H_(3)PO_(4)(aq)+4Ag(s)+4HNO_(3)(aq)`
b. `H_(3)PO_(2)(aq)+2CuSO_(4)(aq)+2H_(2)O(l) rarr H_(3)PO_(4)(aq)+2Cu(s)+H_(2)SO_(4)(aq)`
c. `C_(6)H_(5)CHO(l)+2[Ag(NH_(3))_(2)]^(o+)(aq)+3overset(Θ)(OH)(aq) rarr C_(6)H_(5)COO^(Θ)(aq)+2Ag(s)+4NH_(3)(aq)+2H_(2)O(l)`
d. `C_(6)H_(5)CHO(l)+2Cu^(2+)(aq)+5overset(Θ)(O)H(aq) rarr` No change observed
What inference do you draw about the behaviour of `Ag^(o+)` and `Cu^(2+)` from these reaction?

Text Solution

Verified by Experts

Reaction (a) and (b) infer that `H_3PO_2` (hypophosporus acid) is a reducing agent and respectively. This also means that both `AgNO_3 and CuSO_4` act as oxidising agent and oxidise `H_3PO_2 " to "H_3PO_4` (phosphoric acid ) .
Reaction (c) indicate that `[Ag(NH_3))_2]^(+)` oxidises `C_6H_5CHO` (benzaldehyde) to `C_6H_6COO^(-)` (benzoate ion) but reaction (d) indicates that `Cu^(2+)` , ions cannot oxidise `C_6H_5CHO " to " C_6H_5COO^(-)` . Thus , we can infer from the above reactions that `Ag^(+)` ion is a stronger oxidising agent than `Cu^(2+)` ion.
Promotional Banner

Topper's Solved these Questions

  • REDOX REACTIONS

    MODERN PUBLICATION|Exercise NCERT FILE Solved (NCERT - Exemplar Problems)) (Multiple Choice Questions (Type - I)|1 Videos
  • REDOX REACTIONS

    MODERN PUBLICATION|Exercise NCERT FILE Solved (NCERT - Exemplar Problems) (Multiple Choice Questions (Type - I)|10 Videos
  • REDOX REACTIONS

    MODERN PUBLICATION|Exercise Conceptual Questions|20 Videos
  • ORGANIC CHEMISTRY: BASIC PRINCIPLES AND TECHNIQUES

    MODERN PUBLICATION|Exercise (Competition File) MULTIPLE CHOICE QUESTIONS ( based on the given. passage/comprehension )|8 Videos
  • S-BLOCK ELEMENTS ( ALKALI AND ALKALINE EARTH METALS )

    MODERN PUBLICATION|Exercise UNIT PRACTICE TEST|13 Videos

Similar Questions

Explore conceptually related problems

4M(s)+overset(Ө)(C)N(aq.)+2H_(2)O(aq.)+O_(2)(g) " " to 4[M(CN)_(2)]^(Ө)(aq.)+4overset(Ө)(O)H(aq.)

Complete the chemical equations : MnO_4^(-) (aq) + S_2O_3^(2-)(aq) + H_2O (l) to

Given the sequence of reactions, NH_(4) NO_(2(aq)) +_OH_((aq))^(-) rarr NH_(4) NO_(2(aq))^(-) + H_(2) O_(l) NH_(4) NO_(2(aq))^(-) rarr N_(2) O_(("g")) + OH_((aq))^(-) The catalyst for the overall reaction is

For the reaction S_(2)O_(3)^(2-)(aq) +2H_(3)O^(+)(aq) hArr S(s)+H_(2)SO_(3)(aq)+H_(2)O(l) Rate =k[H_(3)O^(+)][S_(2)O_(3)^(2-)] Reaction is fastest in

MODERN PUBLICATION-REDOX REACTIONS -NCERT FILE Solved (Textbook Exercises)
  1. Whenever a reaction between an oxidising agent and a reducing agent is...

    Text Solution

    |

  2. How do you count for the following observations ? (a) Though alkali...

    Text Solution

    |

  3. Identify the substance oxidised, reduced , oxidising agent and reducin...

    Text Solution

    |

  4. Consider the reaction: 2S(2)O(3)^(2-)(aq)+I(2)(s) rarr S(4)O(6)^(2-)...

    Text Solution

    |

  5. Justify giving reaction that among halogens, fluorine is the best oxid...

    Text Solution

    |

  6. Why does the following reaction occur? XeO(6)^(4-)(aq)+2F^(Θ)(aq)+6H...

    Text Solution

    |

  7. Consider the reactions: a. H(3)PO(2)(aq)+4AgNO(3)(aq)+2H(2)O(l) rarr...

    Text Solution

    |

  8. Balance the following redox reactions by ion electron method: a. MnO...

    Text Solution

    |

  9. Balance the following equations in basic medium by ion-electron method...

    Text Solution

    |

  10. What sort of informations can you draw from the following reaction? ...

    Text Solution

    |

  11. The Mn^(3+) ion is unstable in solution and undergoes disproportionati...

    Text Solution

    |

  12. Consider the elements : Ca, Na, I and F Identify the elements tha...

    Text Solution

    |

  13. Chlorine is used purify drinking water . Excess of chlorine is harmful...

    Text Solution

    |

  14. Refer to the periodic table given in your book and now answer the foll...

    Text Solution

    |

  15. In Ostwald's process for the manufacture of nitric acid, the first ste...

    Text Solution

    |

  16. Using the standard electrode potentials given is the Table 1 predict i...

    Text Solution

    |

  17. Predict the products of electrolysis each of the following : (i) An ...

    Text Solution

    |

  18. i) Arrange the following metals in the order in which they displace ea...

    Text Solution

    |

  19. Given the standard electrode potentials , K^(+)|K=-2.93V, Ag^(+) |Ag...

    Text Solution

    |

  20. Depict the galvanic cell in which the reaction Zn(s) +2Ag^(+)(aq)rarr ...

    Text Solution

    |