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Which of the following species is not pa...

Which of the following species is not paramagnetic?

A

NO

B

CO

C

`O_(2)`

D

`B_(2)`

Text Solution

Verified by Experts

The correct Answer is:
B

`NO to `one unparied electron is present in `pi^(**)` molecular orbit hence paramagnetic
`CO+ KK sigma (2s)^(2)(pi2p_(x))^(2)`
`=(pi 2p_(y))^(2)(sigma 2p_(z))^(2) sigma^(**) (2s)^(2)` no unparied electron hence diamagnetic.
(c) `O_(2) sigma (1s)^(2) sigma^(**) (1s)^(2) sigma (2s)^(2) sigma^(**) (2s)^(2) sigma (2p_(z))^(2)`
`pi(2p_(x))^(2)=pi(2p_(y))^(2) pi^(**) (2p_(x))^(1)=pi(2p_(y))^(1)`
two unparied electron hence paramagnetic.
`B_(2) to KK sigma (2s)^(2) sigma^(**) (2s)^(2) pi (2p_(x))^(1) =pi(2p_(y))^(1)`
`B_(2)` contains two unpaired electrons hence paramagnetic.
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DISHA PUBLICATION-CHEMICAL BONDING AND MOLECULAR STRUCTURE -EXERCISE-2: CONCEPT APPLICATOR
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