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How would you account for the following ...

How would you account for the following ?
(i) Among lanthanoids, Ln (III) compounds are predominant. However, occasionally in solutions or in solid compounds, +2 and +4 ions are also obtained.
(ii) The `E^@(M^(2+)| M)` for copper is positive (0.34V). Copper is the only metal in the first series of transition elements showing this behaviour.
(iii) The metallic radii of the third (5d) series of transition metals are nearly the same as those of the corresponding members of the second series.

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MODERN PUBLICATION-D AND F-BLOCK ELEMENTS-REVISION EXERCISES ( SHORT ANSWER QUESTION)
  1. Zn^(2+) salt are white while Cu^(2+) salts are blue. Assign reason.

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  2. Calculate the number of unpaired electrons in Cr^(3+) and V^(3+) io...

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  3. How will you account for the following: (a) Actinoids exhibit more num...

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  4. (i) What are interstitial compounds ? (ii) Transition metals show good...

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  5. (a) Define transition metals. (b) Why do transition metals form colour...

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  6. (a) What is lanthanoid contraction and write its consequences ? (b) Dr...

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  7. (a) Why are Zn, Cd and Hg not regarded as transition metals? (b) Why d...

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  8. (a) How will you prepare KMnO4 from pyrolusite ore ? (b) Complete the...

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  9. (a) Why do transition metals act as good catalysts? (b) Why do transit...

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  10. (a) Indicate the steps in the preparation of K2Cr2O7 from chromite ore...

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  11. When MnO2 is fused with KOH in the presence of KNO2 as an oxidising ag...

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  12. Give reasons for the following: (i) Transition elements and their co...

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  13. Give reasons for the following: (i) Transition metals form alloys....

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  14. How would you account for the following? (i) Cr^(2+) is reducing...

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  15. How would you account for the following ? (i) Among lanthanoids, ...

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  16. Explain the following observations: (i) Many of the transition element...

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  17. Why do the transition elements have higher enthalpies of atomisation? ...

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  18. (a) How would you account for the following: (i) The chemistry of ...

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  19. Complete and balance the following chemical equations: (a) Fe^(2+) ...

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  20. Give reason for the folloiwng : (a) E("value")^(@) for Mn^(3+)//Mn^(...

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