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30 cc of M/3 HCl, 20cc of M/2 HNO(3) and...

30 cc of `M/3` HCl, 20cc of `M/2` `HNO_(3)` and 40 cc of `M/4 NaOH` solutions are mixed and the volume was made upto `1 dm^(3)`. The pH of the resulting solution is :

A

2

B

1

C

3

D

8

Text Solution

Verified by Experts

The correct Answer is:
A

Total milli equivalent of `h^(+) = 20 xx (1)/(2) + 30 xx (1)/(3) = 20`
Total milliequivalent of `OH^(-) = 40 xx (1)/(4) = 10`
Thus, milliequivalents of `H^(+)` left `= 20 - 10 = 10`
Total volume of solution `= 1 dm^(3) = 1000 ml`
`:. [H^(+)] = (10)/(1000) = 10^(-2)`
`rArr pH = -log[H^(+)] = -log [10^(-2)] = 2`.
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