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Which of the following complex will give...

Which of the following complex will give white ppt. with `BaCl_(2)` solution ?

A

`[Co(NH_(3))_(4)SO_(4)]NO_(2)`

B

`[Cr(NH_(3))_(5)SO_(4)]Cl`

C

`[Cr(NH_(3))_(5)Cl]SO_(4)`

D

Both (b) and (c )

Text Solution

Verified by Experts

The correct Answer is:
C
`[Cr(NH_(3))_(5)Cl]SO_(4) rarr [Cr(NH_(3))_(5)Cl]^(2+)+SO_(4)^(2-)`
`[Cr(NH_(3))_(5)Cl]^(2+)+SO_(4)^(2-)+BaCl_(2) rarr [Cr(NH_(3))_(5)Cl]Cl_(2)+BaSO_(4)+HCl`
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ERRORLESS -COORDINATION CHEMISTRY-ORDINARY THINKING Objective Questions (Isomerism and Magnetic properties)
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  2. The spin only magnetic moment of Mn^(4+) ion is nearly

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  3. Amongst [NiCl(4)]^(2-), [Ni(H(2)O)(6)]^(2+), [Ni(PPh(3))(2)Cl(2)], [Ni...

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  4. The spin-only magnetic moment of [CrF(6)]^(4) ( atomic number of Cr is...

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  5. What is the magnetic moment of K(3)[FeF(6)] ?

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  6. How many unpaired electrons are present in the central metal ion of [C...

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  7. The reaction [Fe(CN)(6)]^(3-) rarr [FeF(6)]^(3-) takes place with

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  8. Which of the following can exhibit geometrical isomerism

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  9. Which of the following is diamagnetic in nature

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  10. Coordination isomerism is caused by the interchange of ligands between...

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  11. Which of the following complex will give white ppt. with BaCl(2) solut...

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  12. In coordination compound [Co(en)(2)Cl(2)]Cl which is false

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  13. Which of the following complex does not show geometrical isomerism

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  14. Which of the following complex does not show optical isomerism

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  15. Which would exhibit co-ordination isomerism

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  16. [Co(NH(3))(4)Cl(2)]^(+) exhibits

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  17. These questions consist of two statements each, printed as Assertion a...

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  18. Assertion: [Co(NO(2))(3) (NH(3))(3)] does not show optical isomerism. ...

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  19. The type of isomerism shown by the complex [CoCl(2)(en)(2)] is -

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  20. Match the metal ions given in Column I with the spin magnetic moments ...

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