Home
Class 12
CHEMISTRY
Expalin the following observations: a....

Expalin the following observations:
a. Benzene is soluble in water whiel both `1,3-` and `1,4-` cyclohexadiene are insouble.
b. Melting point of benzene `(32K)` is much higher than both `1,3-` and `1,4-` cyhexadiences.
c. `P-` Xylene has higher metling point than `o-` and `m-` xylenes.

Text Solution

Verified by Experts

a. The delocalised `6pi oveline(e)'s` in benzene are more easily polarised resulting in greater van der Walls attractive forces to `H_(2)O` hence more soulle.
b. Benzene can be packed symmetrically in its crystal latice because benzene is a plannar moleucule.
b. Benzene can be packed symmetrically in its crystal latice because benzene is a planar moleucule.
c. `p-` Xylene has a symmetrical structure and can fit better into the crystal lattice than the `o-` or `m-` isomers.
Promotional Banner

Topper's Solved these Questions

  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY|Exercise Exercises Subjective Type|4 Videos
  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY|Exercise Exercises Subjective|17 Videos
  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY|Exercise Solved Examples|21 Videos
  • APPENDIX INORGANIC VOLUME 2

    CENGAGE CHEMISTRY|Exercise Short Answer Type|179 Videos
  • BIOMOLECULES

    CENGAGE CHEMISTRY|Exercise Exercises Archives (Analytical And Descriptive)|8 Videos
CENGAGE CHEMISTRY-AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES -Solved Problems
  1. Answer the following : a. Which of the following H will have lower ...

    Text Solution

    |

  2. Distinguish chemically between the following: i. (a) Cyclohexane, (b...

    Text Solution

    |

  3. Expalin the following observations: a. Benzene is soluble in water w...

    Text Solution

    |

  4. Some alternate strucres proposed for benzene are given. Indicate for e...

    Text Solution

    |

  5. Arrange the following in decreasing order of ((m)/(o + p)) ratio. a...

    Text Solution

    |

  6. Give the principal product on bromination with Br(2)//FeBr(3) of the...

    Text Solution

    |

  7. Give the decreasing order of ((o + p)/(m)) ratio for the nitration of...

    Text Solution

    |

  8. Give major products of the following:

    Text Solution

    |

  9. Give the decreasing order of (o+p)/(m) ratio of the reactions or decre...

    Text Solution

    |

  10. Identify compound (A) How many isomers including geometrical isomers a...

    Text Solution

    |

  11. Identify (A).

    Text Solution

    |

  12. Give the products of the following: i. Benzene + Cylohexanol (BF(3),...

    Text Solution

    |

  13. a. Show that reaction of o- bromogluro benzene with Mg produces benzye...

    Text Solution

    |

  14. When three isomeric chlorotounes are treated with KNH(2) in liquid NH(...

    Text Solution

    |

  15. Give the order of reactivity towards SN^(2) reaction of the followig: ...

    Text Solution

    |

  16. Give the order of reactivity towards SN^(1) reaction of the followig: ...

    Text Solution

    |

  17. Give the order of SN^(-1) of SN^(-1) and SN^(2) displacement of haloge...

    Text Solution

    |

  18. Give the order of reactivity towards E2 dehydrohalo-genation of the fo...

    Text Solution

    |

  19. Give the order of reactivity towards SN^(-1) solvoloysis of the follow...

    Text Solution

    |

  20. Give the order of reactivityh towards SN^(1) reaction of the following...

    Text Solution

    |