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On the basis of Valence bond theory acco...

On the basis of Valence bond theory account for the hybridization, shape and magnetic property of cuprammonium ion.

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`Cu^(2+) ………….. [Ar] 3d^9 4s^0`

Under the influence of approaching `NH_3` ligand an `1e^-` from 3d gets excited to 4p.

The four empty orbitals undergo dsp-hybridization to form four hybrid orbitals of equal energy.
The orbitals of the ligand which contain lone pair of electrons overlap with hybrid orbitals `Cu^(2+)` ion to form co-ordinate bond.

Shape ........ squar planar
Or
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OSWAAL PUBLICATION-CO-ORDINATION COMPOUNDS-TOPIC-2 (WERNER.S THEORY BONDING IN CO-ORDINATION COMPOUND , VBT, CFT AND IMPORTANCE OF CO-ORDINATION COMPOUNDS) (Very Answer Type Questions)
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  2. With the help of valence bond theory account for the geometry and magn...

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  3. Write any three postulates of Werner's theory of complexes.

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  4. Using VBT, explainthe geometry and magnetic property of [Ni(CN)(4)]^(-...

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  5. Using valence bond theory explain geometry, hybridisation and magnetic...

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  6. Mention any two applications of co-ordination compounds.

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  7. What is crystal field splitting?

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  8. Salient features of Molecules Orbital Theory (MOT)

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  9. With the help of VBT explain the hybridisation in tetracarbonyl nickel...

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  10. Discuss briefly giving an example in each case the role of co-ordinati...

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  11. Aqueous copper sulphate solution (blue in colour) gives (i) a green pr...

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  12. Explain the hybridisation, geometry and magnetic property of [Ni(Cl)(4...

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  13. Which of the following overlaping of atomic orbital will not be allowe...

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  14. On the basis of Valence bond theory account for the hybridization, sha...

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  15. With the help of VBT explain the geometry of K4 [Fe(CN)6 and predict i...

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  16. What is meant by stability of a co-ordination compound in solution ? S...

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  17. What is crystal field splitting energy ? How does the magnitude of Del...

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  18. Just like human beings, plants also need various nutrients for their h...

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  19. Who is the father of co-ordination chemistry?

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