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Explain briefly how +2 state becomes mor...

Explain briefly how +2 state becomes more and more stable in the first half of the first row transition elements with increasing atomic number?

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Element (+2 state)`""_(21)Se^(2+) ""_(22)Ti^(2+) ""_(23)V^(2+) ""_(24)Cr^(2+) ""_(25)Mn^(2+)` Electronic configuration `3d^1 3d^2 3d^3 3d^4 3d^5`.
  In all the elements listed, the removal of two 4s-electrons (in `Cr^(2+)`, i.e., from 4s and le from 3d), the 3d-orbitals get gradually occupied. Since, the number of empty d-orbitals increases with increase in atomic number of cations, so the stability of the cations `(M^(2+))` increases from `Sc^(2+)` to `Mn^(2+)`.
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OSWAAL PUBLICATION-D - BLOCK ELEMENTS F - BLOCK ELEMENTS -TOPIC-1 (D - BLOCK ELEMENTS, THEIR PROPERTIES AND COMPONDS)(SHORT ANSWER TYPE QUESTIONS - I)
  1. d-block elements form complex compounds, Give reason.

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  2. Transition elements show high melting points. Why?

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  3. Explain briefly how +2 state becomes more and more stable in the first...

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  4. Name be oxo-metal anions of the first series of the transition metals ...

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  5. What are the characteristics of the transition elements and why are th...

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  6. In what way is the electronic configuration of transition elements dif...

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  7. How is potassium permanganate ( KMnO4) prepared from MnO2 ? write the ...

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  8. Write the structure of MnO4^(2-) and MnO(4)^(-) ions.

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  9. Explain why: (i) E^0 for Mn^(3+)//Mn^(2+) couple is more positive th...

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  10. Complete the following chemical equations: (i) MnO(4)^(-) (aq) + S2O...

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  11. Assign reasons for the following: (i) Copper (I) ion is not known in...

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  12. Assign reasons for each of the following: (i) Transition metals gene...

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  13. How would you account for the following: (i) Cr^(2+) is reducing in ...

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  14. State reasons for the following: (i) Cu(I) ion is not stable in an a...

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  15. Explain giving reasons : (i) Transition metals and their compounds g...

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  16. Account for the following: (i) Cu^(+) ions are not stable in aqueous s...

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  17. How would you account for the following: (i) The atomic radii of the...

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  18. Name the reaction that takes place when a mixture of potassium dichrom...

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  19. Account for the following: (i) In the series Sc to Zn, the enthalpy ...

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  20. Account for the following: (i) Transition elements exhibit higher en...

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