Home
Class 12
CHEMISTRY
Account for the following : (i) IC l i...

Account for the following :
(i) `IC l` is more reactive than `I_(2)`.
(ii) Fluorine never acts as the central atom in polyatomic interhalogen compounds.
(iii) Halogens are strong oxidising agents.

Text Solution

Verified by Experts

(i) `IC l` is more reactive than `I_(2)` : It is because `I-Cl` bond is comparatively weaker than `I-I` Bond.
(ii) Fluorine never acts as the central atom in polyatomic interhalogen compounds because of its high electronegativity and high ioonisation energy.
(iii) Halogens are strong oxidizing agents because they are only one electron less to attain noble gas configuration. Thus, they easily accept electrons to form halide ions.
Promotional Banner

Topper's Solved these Questions

  • P - BLOCK ELEMENTS

    OSWAAL PUBLICATION|Exercise TOPIC - 4 (GROUP - 18 ELEMENTS, THEIR PROPERTIES AND SOME IMPORTANT COMPOUNDS)(VERY SHORT ANSWER TYPE QUESTIONS)|36 Videos
  • P - BLOCK ELEMENTS

    OSWAAL PUBLICATION|Exercise TOPIC - 4 (GROUP - 18 ELEMENTS, THEIR PROPERTIES AND SOME IMPORTANT COMPOUNDS)(SHORT ANSWER TYPE QUESTIONS)|7 Videos
  • P - BLOCK ELEMENTS

    OSWAAL PUBLICATION|Exercise TOPIC - 3 (GROUP - 17 ELEMENTS, THEIR PROPERTIES AND SOME IMPORTANT COMPOUNDS)(SHORT ANSWER TYPE QUESTIONS)|11 Videos
  • ORGANIC COMPOUNDS CONTAINING NITROGEN

    OSWAAL PUBLICATION|Exercise CYANIDES , ISOCYANIDES AND DIAZONIUM SALTS PREPARATION , PHYSICAL AND CHEMICAL PROPERTIES USES ( Long Answer Type Questions-II )|3 Videos
  • POLYMERS

    OSWAAL PUBLICATION|Exercise LONG ANSWER TYPE QUESTIONS - II|2 Videos

Similar Questions

Explore conceptually related problems

How would you account for the following : (i) The electron gain enthalpy with negative sign is less for oxygen than that for sulphur. (ii) Phosphorus shows greater tendency for catenation than nitrogen. (iii) Fluorine never acts as the central atom in polyatomic interhalogen compounds.

Give reason: (i) ICI is more reactive than I_2 . (ii) Fluroine exhibit only -1 oxidation state. (iii) H-F is liquid but other hydrogen halides are gases.

Account for the following : (i) Ammonia is more basic than phosphine. (ii) Elements of Group - 16 generally show lower value of first ionisation enthalpy compared to the elements in the corresponding periods of Group - 15. (iii) Electron pair gain enthalpy with (-)ve sign for fluorine is less than that for chlorine.

Account for the following : (i) PCl_(5) is more covalent than PCl_(3) . (ii) Iron on reaction with HCl forms FeCl_(2) and not FeCl_(3) . (iii) The two O-O bond lengths is the ozone molecule are equal.

Account for the following : (i) Bi(V) is a stronger oxidizing agent than Sb(V). (ii) N-N single bond is weaker than P-P single bond. (iii) Noble gases have very low boiling points.

Account for the following : (i) PCl_(5) can act as an oxidising agent but not as a reducing agent. (ii) Halogens are coloured.

Suggest a possible reason for the following observations : (i) In the solid state, PCl_(5) behave as an ionic species. (ii) H_(2)S is more acidic than water. (iii) Fluorine forms the largest number of interhalogen compounds amongst the halogens.

How are the following interhalogen compounds prepared? (i) ClF_(3) (ii) ICl (iii) BrF_(5) .

How would you account for the following : (i) H_(2)S is more acidic than H_(2)O ? (ii) The N - O bond in NO_(2)^(-) is shorter than the N - O bond in NO_(3)^(-) . (iii) Both O_(2) and F_(2) stabilize high oxidation states but the ability of oxygen to stabilize the higher oxidation state exceeds that of fluorine.

Give reasons for the following : (i) (CH_(3))_(3)P=O exists but (CH_(3))_(3)N=O does not. (ii) Oxygen has less electron gain enthalpy with negative sign than sulphur. (iii) H_(3)PO_(2) is a stronger reducing agent than H_(3)PO_(3) .