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Knowing the electron gain enthalpy value...

Knowing the electron gain enthalpy values for `O to O^(-)` and `O to O^(2-)` as -141 and 702 kj mol-1 respectively, how can you account for the formation of a large number of oxides having `O^(2-)` species and not `O^(-)` ?

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The values of electron gain enthalpy suggest that formation of `O^(2-)` is endothermic. However, `O^(2-)` has most stable configuration in `s_2 np_6`. In solid state, the lattice energies of the oxides having `O^(2-)` anions are very high which compensates the positive electron gain enthalpy of oxide (`O^(2-)`) formation. Thus, more oxides with `O^(2-)` ion are formed.
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KUMAR PRAKASHAN-THE P-BLOCK ELEMENTS -SECTION-C TEXTUAL EXERCISE
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  2. Why is dioxygen a gas but sulphur a solid ?

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  3. Knowing the electron gain enthalpy values for O to O^(-) and O to O^(2...

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  5. Write the conditions to maximise the yield of H2SO(4) by Contact proc...

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  6. How is SO2 an air pollutant ?

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  7. Why are halogens strong oxidising agents ?

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  8. Explain why fluorine forms only one oxoacid, HOF.

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  9. Explain why inspite of nearly the same electronegativity, nitrogen for...

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  10. Write two uses of ClO(2)

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  11. Why are halogens coloured ?

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  12. Write the reactions of F2 and Cl2 with water.

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  13. How can you prepare Cl2 from HCl and HCl from Cl2 ? Write reactions on...

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  14. What inspired N. Bartlett for carrying out reaction between Xe and PtF...

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  15. What are the oxidation states of phosphorus in the following: (i) H(...

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  16. Write balanced equations for the following : (i) NaCl is heated with...

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  17. How are xenon fluorides XeF2, XeF(4) and XeF(6) obtained ?

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  18. With what neutral molecule is ClO^(-) isoelectronic ? Is that molecule...

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  19. How are XeO3 and XeOF4 prepared ?

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  20. Arrange the following in the order of property indicated for each set ...

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