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The reagent which forms crystalline osaz...

The reagent which forms crystalline osazone derivatives with glucose is 

A

Fehling solution

B

Phenyl hydrazine

C

Benedict's solution

D

Hydroxylamine

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The correct Answer is:
B
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D-tagatose is a 2-ketohexose which forms same osazone as D-galactose. What is the structure of D-tagatose

Monosaccharides have -CHO (or C=O) and -OH groups, so they undergo usual oxidation and reduction. Further, monosaccharides from osazone when treated with excess of phenylhdrazine (3 equivalents). In osazone formation only the first two carbon atoms are involved. Thus monosaccharidxes having identical configuration on reset of C atoms except first two will form same osazone, as is the case with glucose and fructose. A, B and C are three hexoses and form same osazone D. Compounds A to D behave as below (A) D overset(HCl)rarr underset(CH_(3)COOH)overset(Zn)rarr D - Fructose (B) A overset(Ni.H_(2))rarr overset(HNO_(3))rarr underset(H_(3)O^(+))overset(Na-Hg)rarr B + C (C ) B overset(HNO_(3))rarr Optically active glycaric acid (D) C overset(HNO_(3))rarr Optically inactive glycaric acid Compound D is an osazone which can be obtained from

Sugars are characterized by the preparation of Osazone derivatives. Which sugars have identical osazones

The reagents which don't react with glucose are I) Schiff's reagent II) Tollen's reagent III) Fehling reagent IV) NaHSO_(3) V) NH_3

The reagent with which ethanol is oxidised to ethanal is

Sugar are characterised by the preparation of osazone derivatives. Which sugar have identical osazones?

Monosaccharides and disaccharides in which aldehyde group is free reduce Tollen's reagent as well as Fehling solution and hence are known as reducing sugars. Carbohydrates react with excess of phcayl kydrazine to yield their crystalline derivatives called oxazones. In osazone formation only the first two carbon atoms are irrelved Osazone on hydrolysis gives same which are reduction with ZnCH_(3)COOH gives a ketose sugar The same osazone is formed by

Monosaccharides and disaccharides in which aldehyde group is free reduce Tollen's reagent as well as Fehling solution and hence are known as reducing sugars. Carbohydrates react with excess of phcayl kydrazine to yield their crystalline derivatives called oxazones. In osazone formation only the first two carbon atoms are irrelved Osazone on hydrolysis gives same which are reduction with ZnCH_(3)COOH gives a ketose sugar Osazone cannot be formed by whihc of the following

Monosaccharides and disaccharides in which aldehyde group is free reduce Tollen's reagent as well as Fehling solution and hence are known as reducing sugars. Carbohydrates react with excess of phcayl kydrazine to yield their crystalline derivatives called oxazones. In osazone formation only the first two carbon atoms are irrelved Osazone on hydrolysis gives same which are reduction with ZnCH_(3)COOH gives a ketose sugar The end product 'Z' in the following sequence of reactions. Glucose, underset(("excess"))overset(Ph. NH.NH_(2))rarr X underset(Delta)overset(H_(2)O//H^(+))rarr Y overset(Zn//AcOH)rarrZ

Which one of the following hydrocarbons will form only one monochloro derivative with Cl_2//hv .

AAKASH SERIES-BIOMOLECULES-OBJECTIVE EXERCISE - 1
  1. On heating glucose with Fehling solution, we get a precipitate whose c...

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  2. Glucose gives silver mirror test with Tollen's reagent. It shows the p...

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  3. The reagent which forms crystalline osazone derivatives with glucose i...

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  4. When glucose is heated with nitric acid the product is

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  5. Glucose when heated with CH(3)OH in presence of dry HCl gas gives a an...

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  6. When hemiacetal reacts with alcohol the product is

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  7. Freshly prepared a-D-glucose solution has specific rotation +111^(@)an...

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  8. Which does not show mutarotation?

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  9. Ring structure of glucose is due to formation of hemiacetal and ring f...

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  10. The wrong statement about glucose is

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  11. Fructose contains

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  12. The fischer projection of glyceraldehyde representing correct configur...

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  13. Which of the following is called as Laevulose?

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  14. The sweetest sugar among the following is

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  15. For naturally occurring fructose, the configuration and sign of specif...

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  16. Glyceraldehyde and Dihydroxy acetone are a pair of

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  17. According to CIP rules, the configuration of (+) - glyceraldehyde can ...

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  18. Accroding to CIP rules, the configuration of chiral carbon atoms in D ...

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  19. Glucose and cane sugar can't be distinguished by

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  20. In which of the following all are disaccharides?

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