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Monosaccharides and disaccharides in whi...

Monosaccharides and disaccharides in which aldehyde group is free reduce Tollen's reagent as well as Fehling solution and hence are known as reducing sugars. Carbohydrates react with excess of phcayl kydrazine to yield their crystalline derivatives called oxazones. In osazone formation only the first two carbon atoms are irrelved Osazone on hydrolysis gives same which are reduction with `ZnCH_(3)COOH` gives a ketose sugar
Osazone cannot be formed by whihc of the following

A

`C_(6)H_(5) - CH (OH)COC_(6)H_(5)`

B

`OHC-CH(OH)-(CH(OH))_(3) - CH_(2)OH`

C

`HOH_(2)C-CO - (CHOH)_(3)-CH_(2)OH`

D

`OHC-CH_(2)-(CH(OH))_(3)-CH_(2)OH`

Text Solution

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The correct Answer is:
D

group and `-CHOH` group must be on adjacent carbon atoms to form osazone
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Monosaccharides and disaccharides in which aldehyde group is free reduce Tollen's reagent as well as Fehling solution and hence are known as reducing sugars. Carbohydrates react with excess of phcayl kydrazine to yield their crystalline derivatives called oxazones. In osazone formation only the first two carbon atoms are irrelved Osazone on hydrolysis gives same which are reduction with ZnCH_(3)COOH gives a ketose sugar The same osazone is formed by

Monosaccharides and disaccharides in which aldehyde group is free reduce Tollen's reagent as well as Fehling solution and hence are known as reducing sugars. Carbohydrates react with excess of phcayl kydrazine to yield their crystalline derivatives called oxazones. In osazone formation only the first two carbon atoms are irrelved Osazone on hydrolysis gives same which are reduction with ZnCH_(3)COOH gives a ketose sugar The end product 'Z' in the following sequence of reactions. Glucose, underset(("excess"))overset(Ph. NH.NH_(2))rarr X underset(Delta)overset(H_(2)O//H^(+))rarr Y overset(Zn//AcOH)rarrZ

Fructose reduces Tollen's reagent due to

What are reducing sugars ?

The acid which reduces Tollen's reagent is

A disaccharide on hydrolysis gives

A disaccharide on hydrolysis gives

Which is a reducing sugar?

The carboxylic acid that reduces Tollen's reagent is

Define reducing and non-reducing sugars.

AAKASH SERIES-CARBOHYDRATES-Practice Sheet-1
  1. Which of the following statements is correct?

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  2. Which of the following reagents is useful to distinguish between gluco...

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  3. Which of the following is correct statement?

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  4. Which of the following statement is/are correct?

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  5. What is /are the major product (s) in the reaction below?

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  6. Which of the following statements is/are correct

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  7. C(6)H(12)O(6) can be glucose or Fructose C(6)H(12)O(6) overset(HCN)rar...

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  8. C(6)H(12)O(6) can be glucose or Fructose C(6)H(12)O(6) overset(HCN)rar...

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  9. C(6)H(12)O(6) can be glucose or Fructose C(6)H(12)O(6) overset(HCN)rar...

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  10. Monosaccharides and disaccharides in which aldehyde group is free redu...

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  11. Monosaccharides and disaccharides in which aldehyde group is free redu...

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  12. Monosaccharides and disaccharides in which aldehyde group is free redu...

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  13. Match the following columns

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  14. Match the following columns

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  15. The minimum number of carbon atoms that should present in a carbohydra...

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  16. The number of chiral centers in the open chain structure of glucose is

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  17. How many chiral centers are present in the product obtained by reactio...

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  18. The no. of chiral carbon atoms present in ketopentose is

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  19. How many chiral carbon atoms are present in beta-D- ribose?

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  20. The number of chiral centers present in fructo furanose is

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