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The melting points and solubility in wat...

The melting points and solubility in water of amino acids are generally higher than that of the corresponding halo acids. Explain.

A

amino acids exist as zwitter ions resulting in strong dipole-dipole attraction

B

amino acids are optically active

C

due to higher molecular mass of -`NH_(2)` group molecular mass of amino acids is higher

D

they interact with water more than halo-acids and have salt like structure .

Text Solution

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The correct Answer is:
A

Amino acids exist as zwitter ions, `H_(3)overset(+)N-CHR-COO^(-)` .Because of this dipolar salt-like character, they have strong dipole-dipole attractions . Hence, their melting points are higher than halo-acids .
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