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If E(cell)^(@) of electrochemical cell=1...

If `E_(cell)^(@)` of electrochemical cell=1.1 V for possessing following chemical reaction, then what is `E_(cell)` ?
`Zn_((S))+Cu_((aq))^(2+)(0.1M) to Zn^(2+)(1M)+Cu_((S))`

A

2.12 V

B

1.8 V

C

1.07 V

D

0.84 V

Text Solution

Verified by Experts

The correct Answer is:
C

According to following reaction, `n=2`.
`E_(cell)=E_(cell)^(@)-(0.0592)/(n)"log"([Zn^(2+)])/([Cu^(2+)])`
`=1.1-(0.0592)/(2)"log"((1.0)/(0.1))`
`=1.1-0.0296log10`
`=1.1-0.296=1.0704V~~1.07V`
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