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E^(@) value of following half-cell in st...

`E^(@)` value of following half-cell in standard conditions are given as follows :
`[E_(Fe^(3+)|Fe^(2+))^(o)=0.77V,E_(Sn^(2+)|Sn)^(o)=-0.14V]` by using such value calculate potential of given reaction ?
`Sn_((S))+2Fe_((aq))^(3+) to 2Fe_((aq))^(2+)+Sn_((aq))^(2+)`.

A

0.91V

B

1.40V

C

1.68V

D

0.63V

Text Solution

Verified by Experts

The correct Answer is:
A

`E^(o)=E_(Fe^(2+)|Fe^(2))^(o)-E_(Sn^(2+)|Sn)^(o)`
`=0.77-(-0.14)=0.91V`.
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Consider the following E^o values : E^o _Fe^(3+)//FE^(2+)o = + 0.77 V E_(Sn^(2+)//Sn) =- 0.14 V Under standard conditions the potential for reaction Sn(s) +2Fe^(3+) (aq) rarr 2Fe^(2+) (sq) + Sn^(2+) (aq) is.

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