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case-I : I2 + H2O2 to O2 + 2I^- +2H^+ ...

case-I : `I_2 + H_2O_2 to O_2 + 2I^- +2H^+`
case-II: `2H^+H_2O_2+ 2OCl^- to Cl_2 + O_2 +2H_2O`

A

In case-I `H_2O_2` act as oxidising agent and in case-II `H_2O_2` act as reducing agent.

B

In both case `H_2O_2` act as reducing agent.

C

In both case `H_2O_2` act as oxidising agent.

D

In case-I `H_2O_2` act as reducing agent and in case-II `H_2O_2` act as oxidising agent.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given problem, we need to analyze the two cases provided and determine the role of hydrogen peroxide (H₂O₂) in each reaction. ### Step-by-Step Solution **Case I: Reaction Analysis** 1. **Write the reaction**: \[ I_2 + H_2O_2 \rightarrow O_2 + 2I^- + 2H^+ \] 2. **Identify oxidation states**: - In \(I_2\), iodine (I) has an oxidation state of 0. - In \(I^-\), iodine has an oxidation state of -1. - In \(H_2O_2\), the oxidation state of oxygen is -1 (for each O). - In \(O_2\), oxygen has an oxidation state of 0. 3. **Determine changes in oxidation states**: - Iodine is reduced from 0 to -1 (gaining electrons). - Oxygen in H₂O₂ is oxidized from -1 to 0 (losing electrons). 4. **Conclusion for Case I**: - Since H₂O₂ causes iodine to be reduced (it gains electrons), H₂O₂ acts as an **oxidizing agent** in this case. **Case II: Reaction Analysis** 1. **Write the reaction**: \[ 2H^+ + H_2O_2 + 2OCl^- \rightarrow Cl_2 + O_2 + 2H_2O \] 2. **Identify oxidation states**: - In \(OCl^-\), chlorine (Cl) has an oxidation state of +1. - In \(Cl_2\), chlorine has an oxidation state of 0. - In \(H_2O_2\), the oxidation state of oxygen is -1 (for each O). - In \(O_2\), oxygen has an oxidation state of 0. 3. **Determine changes in oxidation states**: - Chlorine is reduced from +1 in \(OCl^-\) to 0 in \(Cl_2\) (gaining electrons). - Oxygen in H₂O₂ is oxidized from -1 to 0 (losing electrons). 4. **Conclusion for Case II**: - Since H₂O₂ causes chlorine to be reduced (it gains electrons), H₂O₂ acts as an **oxidizing agent** in this case as well. ### Final Conclusion - In both cases, H₂O₂ is acting as an **oxidizing agent** because it causes the reduction of iodine in Case I and the reduction of chlorine in Case II. ### Answer The correct answer is that H₂O₂ is acting as an oxidizing agent in both cases. ---
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