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The major product of the following chemi...

The major product of the following chemical reaction is:
`CH_3CH_2CNoverset(overset(((1)H_3O^+,Delta))((2)SOCl_2))underset((3)pd//BaSO_4,H_2)rarr?`

A

`CH_3CH_2CH_3`

B

`CH_3CH_2CH_2OH`

C

`(CH_3CH_2CO)_2O`

D

`CH_3CH_2CHO`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given problem, we need to analyze the chemical reaction step by step. The reaction involves a compound with a cyanide group and goes through two main steps: first, the conversion of the cyanide to an aldehyde, and then the reduction of that aldehyde to an alcohol. ### Step 1: Reaction with H3O+ (Hydronium Ion) The starting compound is `CH3CH2C≡N` (a nitrile). When this compound reacts with `H3O+`, it undergoes hydrolysis. In this step, the cyanide group (C≡N) is converted into an aldehyde (C=O). This reaction is known as the hydrolysis of nitriles. The reaction can be summarized as follows: \[ CH_3CH_2C≡N + H_3O^+ \rightarrow CH_3CH_2C(=O)H \] This gives us the product: \[ CH_3CH_2CHO \] which is butanal (an aldehyde). ### Step 2: Reduction with Pd/BaSO4 and H2 In the second step, the aldehyde formed (butanal) is reduced to an alcohol using palladium on barium sulfate (Pd/BaSO4) in the presence of hydrogen gas (H2). This reduction converts the carbonyl group (C=O) of the aldehyde to a hydroxyl group (–OH), yielding a primary alcohol. The reaction can be summarized as follows: \[ CH_3CH_2CHO + H_2 \xrightarrow{Pd/BaSO_4} CH_3CH_2CH_2OH \] This gives us the product: \[ CH_3CH_2CH_2OH \] which is butanol (a primary alcohol). ### Final Product Thus, the major product of the reaction sequence is: \[ CH_3CH_2CH_2OH \] which is butanol. ### Summary of Steps: 1. **Hydrolysis of Nitrile**: Convert `CH3CH2C≡N` to `CH3CH2CHO` (butanal). 2. **Reduction of Aldehyde**: Convert `CH3CH2CHO` to `CH3CH2CH2OH` (butanol).
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JEE MAINS PREVIOUS YEAR-JEE MAIN 2021-SECTION-A
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  2. Which statement is correct?

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  10. The orbital having two radial as well as two angular nodes is

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  11. Match List - I with List- II Choose the most appropriate answ...

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  12. Identify the major products A and B respectively in the following reac...

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  13. Given below are two statements : Statement I : A mixture of chloroform...

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  14. For the given reaction :

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  15. On treating a compound with warm dil. H2 SO4, gas X is evolved which t...

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  16. Which of the following is 'a' FALSE statement

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