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According to Bohr's atomic energy :- (...

According to Bohr's atomic energy :-
(A) Kinetic energy of electron is ` prop (Z^(2))/(n^(2))`.
(B) The product of velocity (v) of electron and principal quantum number(n), `'vn' prop Z^(2)`.
(C) Frequency of revolution of electron in an orbit is ` prop (Z^(3))/(n^(3))`.
(D) Coulombic force of attraction on the electron is ` prop (Z^(3))/(n^(4))`.
Choose the most appropriate answer from the option given below:

A

(C) only

B

(A) only

C

(A),(C) and (D) only

D

(A) and (D) only

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze each statement based on Bohr's atomic theory and determine which ones are correct. ### Step-by-Step Solution: 1. **Kinetic Energy of Electron (Statement A)**: - According to Bohr's model, the kinetic energy (KE) of an electron in an orbit is given by the formula: \[ KE = \frac{13.6 \, Z^2}{n^2} \, \text{eV} \] - This indicates that the kinetic energy is directly proportional to \(Z^2\) and inversely proportional to \(n^2\). - **Conclusion**: Statement A is **True**. 2. **Product of Velocity and Principal Quantum Number (Statement B)**: - The velocity \(v\) of an electron in a given orbit is given by: \[ v = \frac{2.18 \times 10^6 \, Z}{n} \, \text{m/s} \] - The product of velocity and principal quantum number \(n\) is: \[ vn = \left(\frac{2.18 \times 10^6 \, Z}{n}\right) n = 2.18 \times 10^6 \, Z \] - This shows that \(vn\) is directly proportional to \(Z\) and not \(Z^2\). - **Conclusion**: Statement B is **False**. 3. **Frequency of Revolution of Electron (Statement C)**: - The frequency \(f\) of an electron's revolution can be derived from its velocity and radius. The formula for frequency is: \[ f = \frac{v}{2\pi r} \] - The radius \(r\) is related to \(n\) and \(Z\) as: \[ r \propto \frac{n^2}{Z} \] - Substituting the expression for \(v\) and \(r\) into the frequency formula gives: \[ f \propto \frac{Z}{n^3} \] - Therefore, the correct relationship shows that frequency is proportional to \(Z^2/n^3\), not \(Z^3/n^3\). - **Conclusion**: Statement C is **False**. 4. **Coulombic Force of Attraction (Statement D)**: - The Coulombic force of attraction \(F\) between the nucleus and the electron can be expressed as: \[ F \propto \frac{Z \cdot e^2}{r^2} \] - The radius \(r\) can be substituted with \(n^2/Z\) to give: \[ F \propto \frac{Z \cdot e^2 \cdot Z^2}{n^4} \propto \frac{Z^3}{n^4} \] - This indicates that the force is indeed proportional to \(Z^3/n^4\). - **Conclusion**: Statement D is **True**. ### Final Answer: The correct statements according to Bohr's atomic theory are A and D. Therefore, the most appropriate answer is **Option D**.
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