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Given below are two statements : St...

Given below are two statements :
Statement I : The identification of `Ni^(2+)` is carried out by dimethyl glyoxime in the presence of `NH_4OH`.
Statement II : The dimethyl glyoxime is a bidentate neutral ligand.
In the light of the above statements, choose the correct answer from the options given below:

A

Statement I is true but Statement II is false.

B

Both Statement I and Statement II are false

C

Statement I is false but Statement II is true

D

Both Statement I and Statement II are true

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze both statements provided in the question regarding the identification of `Ni^(2+)` using dimethyl glyoxime (DMG) and the nature of DMG as a ligand. ### Step-by-Step Solution: 1. **Understanding Statement I**: - Statement I claims that the identification of `Ni^(2+)` is carried out by dimethyl glyoxime in the presence of `NH_4OH`. - This statement is **correct**. Dimethyl glyoxime (DMG) is indeed used to detect nickel ions (`Ni^(2+)`). When nickel(II) ions react with DMG in the presence of ammonium hydroxide, a red precipitate of nickel dimethylglyoxime complex is formed, which confirms the presence of nickel. 2. **Understanding Statement II**: - Statement II claims that dimethyl glyoxime is a bidentate neutral ligand. - This statement is **incorrect**. While DMG is a bidentate ligand because it can coordinate to a metal ion through two donor atoms (the nitrogen atoms), it is not neutral. The structure of DMG contains an anionic form (due to the presence of a negative charge on the oxygen in the deprotonated form), which makes it a negatively charged ligand. 3. **Conclusion**: - From the analysis, we conclude that Statement I is correct and Statement II is incorrect. Therefore, the correct answer to the question is that one statement is correct and the other is incorrect. ### Final Answer: - **One statement is correct and the other is incorrect.**
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