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The major product of the following react...

The major product of the following reaction is
`CH_3CH_2CH= CH_2 underset(Rh "catalyst")overset(H_2//CO)(to)`

A

`CH_3CH_2CH=CH - CHO`

B

`CH_3CH_2 undersetoverset(|)(CHO)(C ) = CH_2`

C

`CH_3CH_2CH_2CH_2CHO`

D

`CH_3CH_2CH_2CHO`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the major product of the given reaction, we need to analyze the reaction conditions and the starting material. ### Step-by-Step Solution: 1. **Identify the Starting Material**: The starting material is `CH3CH2CH=CH2`, which is 1-butene. It has a double bond between the second and third carbon atoms. 2. **Understand the Reaction Conditions**: The reaction is carried out in the presence of a Rhodium (Rh) catalyst and involves hydrogen (H2) and carbon monoxide (CO). This suggests that the reaction is likely an OXO process (also known as hydroformylation). 3. **Oxo Process Overview**: In the OXO process, alkenes react with carbon monoxide and hydrogen to form aldehydes. The reaction typically adds a formyl group (-CHO) to the alkene, resulting in an increase in the carbon chain length. 4. **Determine the Product**: - The alkene (1-butene) has 4 carbon atoms. - In the OXO process, one carbon atom is added from carbon monoxide (CO) to the alkene. - Therefore, the total number of carbon atoms in the product will be 4 (from the alkene) + 1 (from CO) = 5 carbon atoms. 5. **Identify the Structure of the Product**: The major product will be an aldehyde with 5 carbon atoms. The possible structure is pentanal (also known as valeraldehyde), which can be represented as: - CH3(CH2)3CHO 6. **Final Answer**: The major product of the reaction is pentanal (or valeraldehyde).
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